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The space-group frequency for approximately 30 000 organic compounds in the NBS Crystal Data Identification File has been calculated for each of the 230 space groups. 75% of the compounds have been reported in only five space groups: P21/c (36.0%), P{\bar 1} (13.7%), P212121 (11.6%), P21 (6.7%) and C2/c (6.6%). In contrast, there are 29 space groups with only one entry and 35 space groups with none at all. Although the space-group frequencies should be fairly representative of their distribution in nature, certain frequencies are over- or under-estimated. An analysis of the metric symmetry for about 30 000 lattices using a matrix technique has revealed that it is not uncommon for the metric symmetry to exceed the reported crystal symmetry. In many of these cases, the structures have been described in space groups of unnecessarily low symmetry. By explicitly checking for the highest possible metric symmetry during the space-group-determination procedure, errors of this type can be prevented.
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