An optically pure P-alkene-ligated Ir^I complex

The asymmetric unit of (P)-chloridobis[(S)-(+)-5-(3,5-dioxa-4-phosphacyclo­hepta­[2,1-a:3,4-a']dinaphthalen-4-yl)dibenz[b,f]azepine]iridium(I)-benzene-pentane (1/1/1), [IrCl(C₃₄H₂₂NO₂P)₂]·C₆H₆·C₅H₁₂, contains two formula units. The two symmetry-independent mol­ecules of the Ir complex have similar conformations and approximate C₂ symmetry, with small deviations arising from slightly different puckering of the seven-membered di­oxa­phospha­cyclo­hepta­di­ene rings. The Ir atoms have trigonal-bipyramidal coordination geometry, with the P atoms in axial positions. The steric strain of the bidentate coordination of the P-alkene ligand through its P and alkene C atoms causes the N atom to have pyramidal geometry, compared with the trigonal-planar geometry observed in the free ligand. The coordination also results in an anti conformation of the binaphthyl and alkene groups within the P-alkene ligand.

S1. Comment

Chiral P-alkene ligands are attracting growing interest in the field of enantioselective catalysis (Defieber et al., 2008). For example, the alkene-phosphoramidite, (S)-(+)-N-(3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4- a']dinaphthalen-4-yl)-dibenz[b,f]azepine, (1) (Briceño & Dorta, 2007; Mariz et al., 2008), was used as a ligand in the Ir-catalysed enantioselective formation of allylic amines from allylic alcohols (70% ee) (Defieber et al., 2007) and for the Rh-catalysed conjugate addition (CA) of arylboronic acids to enones with up to 99% ee (Drinkel et al., 2010). In the latter case, the fully characterized monomeric Rh precatalysts, (2), of composition [RhCl(κ¹-P-alkene)(κ²-P-alkene)] bearing two equivalents of P-alkene ligand (1), displayed exclusive cis coordination of the P atoms and a square-planar coordination environment. Roggen & Carreira (2010) recently described the crystal structure of a similar monomeric Ir iodo complex of composition [IrI(P-alkene)₂] bearing, in a trans arrangement, the achiral variant of the P-alkene ligand (1), i.e. featuring the 2,2'-biphenol motif instead of the chiral auxiliary (S)-binaphthol. This complex is a competent catalyst for the stereospecific substitution of chiral allylic alcohols with sulfamic acid to afford optically active allylic amines with enantiospecificities >98%. Breher et al. (2004) described a related crystal structure of an achiral [IrCl(P-alkene)₂] complex also displaying trans or axial positioning of the P atoms in the trigonal–bipyramidal coordination environment. We note that the aforementioned pentacoordinate Ir complexes are per se chiral, possessing stereogenic Ir centres, but obviously without the use of enantiodiscriminating auxiliaries they are obtained as racemates. Here, we disclose the crystal structure of such a complex that is optically pure. The enantiomerically pure ligand (S)-(1) was used to synthesize the title complex, (3), and to our surprise its formation was perfectly diastereospecific based on NMR spectroscopy [possible diastereomers are (M,S,S) and (P,S,S); see also the pair of enantiomers of (3) depicted in the scheme]. Single-crystal X-ray analysis then allowed us to determine the absolute configuration at Ir, which is (P).

The asymmetric unit of (3) contains two molecules of the Ir complex, two of benzene and two of pentane. The two independent molecules of the Ir complex have largely similar conformations (Fig. 1), with the largest differences being in the orientations of the binaphthyl rings as a result of different puckering of the seven-membered phosphadioxa rings. The Cremer & Pople (1975) puckering parameters for the seven-membered rings are listed in Table 2 and show that the total puckering amplitude, Q, is somewhat different for the two seven-membered rings in each independent Ir complex molecule, but that the pattern is similar across the two molecules. An overlay of the two molecules is shown in Fig. 2, which demonstrates that small variations in the ring puckering have a significant effect on the positions of the atoms at the remote ends of the naphthyl rings. The molecules are approximately C₂ symmetric about the Ir—Cl axis, although the different ring puckering in the two seven-membered rings diminishes the exactness of the fit to C₂ symmetry. In contrast, the corresponding Ir complex with biphenyl groups in the P-alkene ligands has crystallographic C₂ symmetry (Roggen & Carreira, 2010).

The coordination environment in the Ir complex of (3) can be considered as trigonal bipyramidal, with the P atoms in axial positions, and the equatorial positions occupied by the Cl atom and the two alkene functions, each of which may be considered as occupying a single site in the formal equatorial trigonal plane. This arrangement parallels the architectures reported by Roggen & Carreira (2010). In each of the independent molecules, the Ir atom lies well within the plane defined by the Cl atom and the four alkene C atoms. The maximum deviations of these six atoms from the mean plane are 0.028 (4) Å for atom C48 in molecule A and 0.081 (5) Å for atom C118 in molecule B. The P—Ir—X bond angles, where X is any equatorial atom, lie in the narrow range 85.66 (12)–94.16 (12)°. Taking the bisector, Y, of each alkene C—Ir—C angle as the effective `bond' position of the alkene group gives Cl—Ir—Y angles in the range 109.85 (12)–112.70 (13)° and Y—Ir—Y angles of 139.31 (17) and 136.10 (17)°. These angles are closer to those required for a trigonal–bipyramidal coordination geometry than those expected for a square-planar arrangement with the Cl atom at the apex, thus indicating that the former is a more suitable description of the coordination geometry of the Ir atoms in (3).

The alkene C—C bond lengths [1.447 (6)–1.453 (6) Å] compare well with those in the complexes reported by Breher et al. (2004) and Roggen & Carreira (2010), and are significantly longer than those of the coordinated alkene in Rh complex (2) [1.405 (9) Å; Drinkel et al., 2010] and the alkene function in the free ligand, (1) [1.34 (2) Å; Mariz et al., 2008], which suggests a relatively high π-basicity of Ir^I (Dewar, 1951; Chatt & Duncanson, 1953). The Ir—P [mean 2.274 (2) Å] and Ir—Cl [mean 2.4453 (15) Å] distances (Table 1), and the dihedral angles between the planes of the naphthyl rings within the binaphthyl units, which are in the range 56.24 (17)–64.62 (13)° across the four independent binaphthyl groups, all fall into the expected ranges [Standard reference?].

The four independent N atoms in the P-alkene ligands of (3) have distinctly pyramidal geometry, with the sum of the bond angles about the N atoms in the range 335.6 (5)–337.0 (5)°. In contrast, the corresponding N atom in the free ligand, (1), has a trigonal-planar geometry, subtending a bond-angle sum of 360 (1)° (Mariz et al., 2008). The pyramidalization of the ligand N atom in (3) is similar to that observed in the bidentate ligand of the Rh complex, (2) (Drinkel et al., 2010), and may be a consequence of steric strain introduced by the bidentate coordination to the Ir atom through the P and alkene C atoms, which effectively creates six-membered boat-shaped chelate rings. The bite angles of the four independent ligands in the structure, P—Ir—Y, where Y is the bisector of each allyl C—Ir—C angle, are in the range 86.51 (13)–87.90 (13)°. When viewed along the P—Ir bond, the P—N bond closely eclipses the Ir—Y vector. Drinkel et al. (2010) discussed the torsion angle Y···N—P···Z, where Z is the midpoint of the bond joining the two naphthyl units in the binaphthyl group. This torsion angle for the bidentate P-alkene ligand in (2) is approximately 180°, which indicates an anti conformation of the binaphthyl and alkene groups, whereas syn conformations are found in the free ligand and the monodentate ligand in (2). The absolute values of the corresponding torsion angles for (3) are in the range 170.8 (2)–179.1 (2)° and also indicate an anti conformation for the bidentate ligands, which is consistent with the previous observations.

The packing of the molecules is fairly unremarkable, with one of each of the independent benzene and pentane solvent molecules lying in narrow channels running parallel to the [010] direction. The remaining solvent molecules occupy interstices between the complex molecules. There are no π–π interactions, with the shortest distance between the centres of gravity of any aromatic rings being approximately 4.0 Å. The shortest contacts of the C—H···π and C—H···O types are also considered to be too long to be indicative of significant attractive interactions.

The use of complex (3) as an enantioselective catalyst for organic transformations is currently being investigated, and results will be published in due course.

S2. Experimental

The title iridium complex, (3), was prepared by adding dropwise a solution of (S)-(1) (1325 mg, 2.610 mmol) in benzene (10.3 g) to a vigorously stirred slurry of [IrCl(coe)₂]₂ (coe = cyclooctene) (585 mg, 0.652 mmol) in benzene (3.6 g). The resulting deep-red solution was stirred for 2 d at 353 K and gradually turned a brighter red. Evaporation of the volatiles followed by washing with pentane and drying in vacuo afforded a beige powder (yield 1350 mg, 74%). Diffraction quality colourless monocrystals were obtained by layering a solution of (3) (50 mg, containing ca 2 equivalents of cocrystallized benzene) in CDCl₃ (0.6 ml) in an NMR tube with pentane (1.2 ml).

S3. Refinement

The asymmetric unit of (3) contains two molecules of the Ir complex, two of benzene and two of pentane. The atomic coordinates were tested carefully for a relationship from a higher-symmetry space group using the program PLATON (Spek, 2009), but none could be found. The solvent molecules may be slightly disordered. A disordered model was not developed, but the bond lengths and angles in the two benzene molecules were restrained to be similar and the C—C distances were restrained to a target value of 1.395 (5) Å. Similarly, the bond lengths and angles in the two pentane molecules were restrained to be similar and the C—C distances were restrained to a target value of 1.520 (4) Å. Neighbouring atoms within one benzene and one pentane molecule were restrained to have similar atomic displacement parameters. All H atoms were placed in geometrically idealized positions and constrained to ride on their parent atoms, with C—H = 0.95 Å for the aromatic H atoms and 1.00 Å for the alkene H atoms, and with U_iso(H) = 1.2U_eq(C). The determined absolute configuration established by the structure determination agreed with that expected from the synthesis [(S)-binaphthyl groups].

Computing details

Data collection: COLLECT (Nonius, 2000); cell refinement: DENZO-SMN (Otwinowski & Minor, 1997); data reduction: DENZO-SMN (Otwinowski & Minor, 1997) and SCALEPACK (Otwinowski & Minor, 1997); program(s) used to solve structure: DIRDIF94 (Beurskens et al., 1994); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97 (Sheldrick, 2008) and PLATON (Spek, 2009).

Figures

	Fig. 1. View of (a) molecule A and (b) molecule B of the Ir complexes of (3), showing the atom-labelling scheme. Displacement ellipsoids are drawn at the 50% probability level. H atoms have been omitted for clarity.
	Fig. 2. Overlay of the two independent complex molecules of (3), generated by matching the positions of the Ir, P, Cl and N atoms. H atoms have been omitted for clarity.

(P)-chloridobis[(S)-(+)-5-(3,5-dioxa-4- phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)- dibenz[b,f]azepine]iridium(I)–benzene–pentane (1/1/1)

Crystal data

[IrCl(C34H22NO2P)2]·C6H6·C5H12	F(000) = 2824
Mr = 1392.97	Dx = 1.469 Mg m^−3
Monoclinic, P21	Mo Kα radiation, λ = 0.71073 Å
a = 22.2716 (1) Å	Cell parameters from 281047 reflections
b = 12.6944 (1) Å	θ = 2.0–25.0°
c = 23.6689 (2) Å	µ = 2.27 mm^−1
β = 109.7487 (4)°	T = 160 K
V = 6298.19 (8) Å^3	Tablet, colourless
Z = 4	0.28 × 0.12 × 0.10 mm

Data collection

Nonius KappaCCD area-detector diffractometer	21763 independent reflections
Radiation source: Nonius FR590 sealed tube generator	20907 reflections with I > 2σ(I)
Horizontally mounted graphite crystal monochromator	Rint = 0.049
Detector resolution: 9 pixels mm^-1	θmax = 25.0°, θmin = 2.2°
ω scans with κ offsets	h = −26→26
Absorption correction: multi-scan (SORTAV; Blessing, 1995)	k = −15→15
Tmin = 0.536, Tmax = 0.649	l = −26→28
99162 measured reflections

Refinement

Refinement on F^2	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.028	w = 1/[σ^2(Fo^2) + (0.0338P)^2 + 7.9338P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.068	(Δ/σ)max = 0.004
S = 1.05	Δρmax = 1.36 e Å^−3
21762 reflections	Δρmin = −1.06 e Å^−3
1610 parameters	Extinction correction: SHELXL97 (Sheldrick, 2008), Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
90 restraints	Extinction coefficient: 0.00036 (5)
Primary atom site location: heavy-atom method	Absolute structure: Flack & Bernardinelli (1999, 2000), with 10122 Friedel pairs
Secondary atom site location: difference Fourier map	Absolute structure parameter: −0.018 (3)

Special details

Experimental. Solvent used: pentane Cooling Device: Oxford Cryosystems Cryostream 700 Crystal Mount: glued on a glass fibre Mosaicity (°.): 0.6780 Frames collected: 913 Seconds exposure per frame: 72 Degrees rotation per frame: 0.6 Crystal-Detector distance (mm): 33.4

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. The restraints used during refinement (see _publ_section_exptl_refinement and _iucr_refine_instruction_details) lead to validation alerts concerning the reported and calculated s.u.s of geometric parameters involving the restrained atoms. This is a consequence of fairly tight restraints being used and the validation suite not having access to the variance–covariance matrix.

Eleven low-angle reflections were omitted from the data set, as they were obscured by the beam stop.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Ir1	0.561043 (7)	0.791769 (12)	0.281867 (7)	0.02116 (5)
Cl1	0.45476 (5)	0.85575 (10)	0.27430 (5)	0.0326 (3)
P1	0.55827 (5)	0.88068 (10)	0.19754 (5)	0.0236 (2)
P2	0.57194 (5)	0.69716 (9)	0.36602 (5)	0.0217 (2)
O1	0.49520 (13)	0.9354 (3)	0.15263 (14)	0.0285 (7)
O2	0.58394 (13)	0.8083 (3)	0.15501 (13)	0.0278 (7)
O3	0.52411 (13)	0.7119 (2)	0.40315 (13)	0.0235 (6)
O4	0.64153 (13)	0.7074 (2)	0.41636 (13)	0.0241 (6)
N1	0.60573 (16)	0.9881 (3)	0.21238 (15)	0.0266 (8)
N2	0.56285 (17)	0.5662 (3)	0.35307 (17)	0.0251 (8)
C1	0.4484 (2)	0.8689 (4)	0.1131 (2)	0.0297 (10)
C2	0.4606 (2)	0.8250 (4)	0.0653 (2)	0.0292 (10)
C3	0.4141 (2)	0.7533 (4)	0.0278 (2)	0.0305 (11)
C4	0.4257 (2)	0.6911 (4)	−0.0176 (2)	0.0375 (12)
H4	0.4661	0.6950	−0.0229	0.045*
C5	0.3801 (3)	0.6268 (5)	−0.0534 (3)	0.0433 (13)
H5	0.3888	0.5862	−0.0835	0.052*
C6	0.3198 (3)	0.6196 (5)	−0.0463 (3)	0.0507 (15)
H6	0.2874	0.5767	−0.0726	0.061*
C7	0.3079 (2)	0.6745 (5)	−0.0012 (3)	0.0449 (14)
H7	0.2677	0.6677	0.0041	0.054*
C8	0.3549 (2)	0.7410 (4)	0.0372 (2)	0.0339 (11)
C9	0.3437 (2)	0.7962 (5)	0.0850 (2)	0.0356 (11)
H9	0.3034	0.7903	0.0904	0.043*
C10	0.3901 (2)	0.8577 (4)	0.1234 (2)	0.0340 (11)
H10	0.3832	0.8921	0.1564	0.041*
C11	0.5795 (2)	0.8371 (4)	0.0963 (2)	0.0295 (10)
C12	0.5208 (2)	0.8490 (4)	0.0531 (2)	0.0285 (10)
C13	0.5195 (2)	0.8831 (4)	−0.0052 (2)	0.0343 (11)
C14	0.4623 (3)	0.9141 (5)	−0.0505 (2)	0.0445 (14)
H14	0.4236	0.9142	−0.0420	0.053*
C15	0.4617 (3)	0.9440 (5)	−0.1062 (3)	0.0557 (16)
H15	0.4229	0.9649	−0.1360	0.067*
C16	0.5192 (3)	0.9435 (6)	−0.1191 (3)	0.067 (2)
H16	0.5186	0.9612	−0.1583	0.080*
C17	0.5754 (3)	0.9179 (6)	−0.0760 (3)	0.0586 (18)
H17	0.6138	0.9199	−0.0850	0.070*
C18	0.5771 (3)	0.8884 (5)	−0.0182 (2)	0.0424 (13)
C19	0.6356 (2)	0.8653 (5)	0.0282 (2)	0.0424 (13)
H19	0.6743	0.8659	0.0197	0.051*
C20	0.6368 (2)	0.8422 (4)	0.0850 (2)	0.0349 (12)
H20	0.6762	0.8299	0.1162	0.042*
C21	0.53263 (19)	0.8033 (4)	0.43898 (18)	0.0231 (9)
C22	0.58436 (19)	0.8068 (4)	0.49120 (18)	0.0228 (9)
C23	0.5966 (2)	0.9045 (4)	0.52451 (19)	0.0236 (9)
C24	0.6522 (2)	0.9229 (4)	0.5732 (2)	0.0271 (10)
H24	0.6840	0.8697	0.5851	0.032*
C25	0.6619 (2)	1.0158 (4)	0.6043 (2)	0.0353 (12)
H25	0.6998	1.0260	0.6376	0.042*
C26	0.6159 (3)	1.0964 (4)	0.5871 (2)	0.0381 (12)
H26	0.6223	1.1603	0.6092	0.046*
C27	0.5616 (2)	1.0826 (4)	0.5382 (2)	0.0351 (11)
H27	0.5311	1.1378	0.5262	0.042*
C28	0.5507 (2)	0.9870 (4)	0.50570 (19)	0.0285 (9)
C29	0.4950 (2)	0.9715 (4)	0.4549 (2)	0.0337 (11)
H29	0.4630	1.0245	0.4442	0.040*
C30	0.4863 (2)	0.8824 (4)	0.4211 (2)	0.0293 (10)
H30	0.4498	0.8741	0.3861	0.035*
C31	0.65312 (19)	0.6662 (3)	0.47414 (19)	0.0236 (9)
C32	0.62563 (19)	0.7135 (3)	0.51154 (18)	0.0211 (9)
C33	0.6342 (2)	0.6641 (3)	0.5686 (2)	0.0245 (10)
C34	0.6024 (2)	0.6999 (4)	0.60767 (19)	0.0275 (10)
H34	0.5773	0.7622	0.5984	0.033*
C35	0.6079 (2)	0.6444 (4)	0.6590 (2)	0.0338 (11)
H35	0.5857	0.6685	0.6844	0.041*
C36	0.6451 (2)	0.5541 (4)	0.6749 (2)	0.0359 (12)
H36	0.6478	0.5169	0.7105	0.043*
C37	0.6777 (2)	0.5192 (3)	0.6393 (2)	0.0325 (11)
H37	0.7041	0.4586	0.6509	0.039*
C38	0.6732 (2)	0.5716 (4)	0.5848 (2)	0.0270 (10)
C39	0.7050 (2)	0.5346 (4)	0.5466 (2)	0.0313 (11)
H39	0.7335	0.4768	0.5590	0.038*
C40	0.6956 (2)	0.5804 (4)	0.4917 (2)	0.0311 (11)
H40	0.7173	0.5549	0.4661	0.037*
C41	0.5868 (2)	1.0638 (4)	0.2494 (2)	0.0298 (11)
C42	0.5676 (2)	1.1643 (4)	0.2262 (2)	0.0405 (12)
H42	0.5674	1.1822	0.1872	0.049*
C43	0.5491 (3)	1.2370 (5)	0.2599 (3)	0.0523 (16)
H43	0.5375	1.3061	0.2447	0.063*
C44	0.5471 (2)	1.2102 (4)	0.3155 (3)	0.0439 (13)
H44	0.5335	1.2602	0.3385	0.053*
C45	0.5649 (2)	1.1107 (4)	0.3376 (2)	0.0331 (11)
H45	0.5623	1.0927	0.3757	0.040*
C46	0.5865 (2)	1.0350 (3)	0.3063 (2)	0.0266 (10)
C47	0.6063 (2)	0.9302 (3)	0.33365 (19)	0.0225 (9)
H47	0.6071	0.9268	0.3761	0.027*
C48	0.65491 (19)	0.8639 (3)	0.3237 (2)	0.0243 (9)
H48	0.6803	0.8258	0.3611	0.029*
C49	0.6951 (2)	0.8960 (4)	0.2885 (2)	0.0263 (10)
C50	0.7600 (2)	0.8697 (4)	0.3092 (2)	0.0348 (11)
H50	0.7763	0.8235	0.3425	0.042*
C51	0.8010 (2)	0.9109 (5)	0.2815 (3)	0.0446 (14)
H51	0.8449	0.8927	0.2962	0.054*
C52	0.7789 (2)	0.9773 (5)	0.2333 (2)	0.0463 (15)
H52	0.8075	1.0067	0.2155	0.056*
C53	0.7144 (2)	1.0013 (5)	0.2106 (2)	0.0382 (11)
H53	0.6985	1.0458	0.1765	0.046*
C54	0.6733 (2)	0.9609 (4)	0.2374 (2)	0.0281 (10)
C55	0.6139 (2)	0.5212 (3)	0.3356 (2)	0.0278 (10)
C56	0.6488 (2)	0.4370 (4)	0.3685 (2)	0.0324 (11)
H56	0.6381	0.4081	0.4009	0.039*
C57	0.6992 (3)	0.3954 (4)	0.3537 (2)	0.0408 (13)
H57	0.7227	0.3374	0.3756	0.049*
C58	0.7151 (2)	0.4389 (5)	0.3067 (3)	0.0431 (13)
H58	0.7502	0.4117	0.2972	0.052*
C59	0.6796 (2)	0.5221 (4)	0.2736 (2)	0.0384 (12)
H59	0.6909	0.5514	0.2417	0.046*
C60	0.6272 (2)	0.5635 (4)	0.2867 (2)	0.0276 (10)
C61	0.5878 (2)	0.6463 (4)	0.24676 (19)	0.0259 (10)
H61	0.6021	0.6603	0.2117	0.031*
C62	0.5190 (2)	0.6516 (4)	0.23000 (19)	0.0241 (10)
H62	0.4980	0.6676	0.1864	0.029*
C63	0.4792 (2)	0.5827 (4)	0.2535 (2)	0.0284 (10)
C64	0.4171 (2)	0.5570 (4)	0.2160 (2)	0.0341 (11)
H64	0.4001	0.5884	0.1775	0.041*
C65	0.3805 (2)	0.4861 (5)	0.2349 (2)	0.0450 (13)
H65	0.3389	0.4689	0.2089	0.054*
C66	0.4035 (2)	0.4403 (4)	0.2909 (3)	0.0406 (12)
H66	0.3786	0.3896	0.3026	0.049*
C67	0.4628 (2)	0.4684 (4)	0.3297 (2)	0.0341 (12)
H67	0.4782	0.4396	0.3690	0.041*
C68	0.5002 (2)	0.5392 (4)	0.3110 (2)	0.0279 (10)
Ir2	0.944388 (7)	0.496363 (12)	0.752585 (7)	0.01917 (5)
Cl2	1.05182 (5)	0.44591 (11)	0.75782 (6)	0.0370 (3)
P3	0.90482 (5)	0.35426 (9)	0.69274 (5)	0.0200 (2)
P4	0.98494 (5)	0.63767 (9)	0.81215 (5)	0.0190 (2)
O5	0.83910 (13)	0.3787 (2)	0.63916 (12)	0.0212 (6)
O6	0.94567 (12)	0.2887 (3)	0.66014 (12)	0.0229 (6)
O7	0.96186 (13)	0.6516 (2)	0.86924 (12)	0.0200 (6)
O8	1.06068 (13)	0.6537 (2)	0.83957 (12)	0.0213 (6)
N3	0.88559 (17)	0.2559 (3)	0.73156 (16)	0.0218 (8)
N4	0.96574 (16)	0.7522 (3)	0.77472 (15)	0.0197 (7)
C71	0.81481 (19)	0.3129 (3)	0.58863 (18)	0.0221 (9)
C72	0.84647 (18)	0.3031 (3)	0.54830 (18)	0.0215 (8)
C73	0.8192 (2)	0.2364 (3)	0.49718 (19)	0.0232 (9)
C74	0.8516 (2)	0.2116 (4)	0.4563 (2)	0.0291 (10)
H74	0.8933	0.2384	0.4633	0.035*
C75	0.8237 (3)	0.1500 (4)	0.4071 (2)	0.0396 (12)
H75	0.8460	0.1349	0.3802	0.048*
C76	0.7619 (3)	0.1086 (4)	0.3958 (2)	0.0417 (13)
H76	0.7422	0.0678	0.3608	0.050*
C77	0.7307 (2)	0.1271 (4)	0.4352 (2)	0.0365 (12)
H77	0.6897	0.0969	0.4281	0.044*
C78	0.7579 (2)	0.1905 (4)	0.48667 (19)	0.0272 (10)
C79	0.7267 (2)	0.2087 (4)	0.5293 (2)	0.0291 (10)
H79	0.6855	0.1796	0.5223	0.035*
C80	0.7544 (2)	0.2667 (3)	0.57953 (19)	0.0254 (10)
H80	0.7336	0.2761	0.6082	0.031*
C81	0.9584 (2)	0.3407 (3)	0.6124 (2)	0.0252 (9)
C82	0.9091 (2)	0.3566 (3)	0.55918 (19)	0.0225 (9)
C83	0.9210 (2)	0.4226 (4)	0.5150 (2)	0.0289 (10)
C84	0.8719 (3)	0.4584 (4)	0.4626 (2)	0.0355 (11)
H84	0.8293	0.4358	0.4550	0.043*
C85	0.8851 (3)	0.5247 (4)	0.4230 (2)	0.0453 (14)
H85	0.8516	0.5478	0.3883	0.054*
C86	0.9477 (3)	0.5590 (5)	0.4329 (3)	0.0534 (16)
H86	0.9564	0.6048	0.4049	0.064*
C87	0.9955 (3)	0.5272 (5)	0.4823 (2)	0.0493 (15)
H87	1.0376	0.5517	0.4886	0.059*
C88	0.9846 (2)	0.4586 (4)	0.5245 (2)	0.0354 (12)
C89	1.0339 (2)	0.4270 (5)	0.5776 (2)	0.0402 (13)
H89	1.0768	0.4451	0.5827	0.048*
C90	1.0212 (2)	0.3715 (4)	0.6213 (2)	0.0326 (11)
H90	1.0545	0.3539	0.6574	0.039*
C91	0.9845 (2)	0.7382 (3)	0.90858 (18)	0.0222 (9)
C92	1.0483 (2)	0.7441 (3)	0.94310 (19)	0.0221 (9)
C93	1.0695 (2)	0.8403 (3)	0.97742 (19)	0.0243 (9)
C94	1.1351 (2)	0.8636 (4)	1.00546 (19)	0.0266 (10)
H94	1.1666	0.8157	1.0021	0.032*
C95	1.1532 (2)	0.9549 (4)	1.0373 (2)	0.0325 (11)
H95	1.1973	0.9705	1.0553	0.039*
C96	1.1080 (2)	1.0256 (4)	1.0437 (2)	0.0337 (11)
H96	1.1215	1.0875	1.0671	0.040*
C97	1.0444 (2)	1.0062 (4)	1.01657 (19)	0.0318 (10)
H97	1.0140	1.0549	1.0211	0.038*
C98	1.0235 (2)	0.9137 (4)	0.9816 (2)	0.0265 (10)
C99	0.9577 (2)	0.8949 (4)	0.9498 (2)	0.0273 (10)
H99	0.9265	0.9421	0.9544	0.033*
C100	0.9390 (2)	0.8102 (4)	0.91313 (19)	0.0248 (10)
H100	0.8951	0.7999	0.8906	0.030*
C101	1.09612 (18)	0.6095 (3)	0.89541 (18)	0.0198 (9)
C102	1.09240 (19)	0.6546 (3)	0.94649 (19)	0.0217 (9)
C103	1.12972 (19)	0.6100 (3)	1.00364 (19)	0.0232 (9)
C104	1.1251 (2)	0.6442 (4)	1.0593 (2)	0.0273 (10)
H104	1.0959	0.6985	1.0597	0.033*
C105	1.1621 (2)	0.5997 (4)	1.1120 (2)	0.0378 (12)
H105	1.1588	0.6244	1.1487	0.045*
C106	1.2048 (2)	0.5184 (4)	1.1129 (2)	0.0409 (13)
H106	1.2308	0.4893	1.1501	0.049*
C107	1.2092 (2)	0.4803 (4)	1.0600 (2)	0.0364 (12)
H107	1.2377	0.4243	1.0608	0.044*
C108	1.1714 (2)	0.5245 (3)	1.0042 (2)	0.0259 (10)
C109	1.1741 (2)	0.4848 (4)	0.9494 (2)	0.0309 (10)
H109	1.2026	0.4289	0.9501	0.037*
C110	1.1370 (2)	0.5244 (3)	0.8956 (2)	0.0270 (10)
H110	1.1385	0.4956	0.8591	0.032*
C111	0.83019 (18)	0.2836 (4)	0.74776 (18)	0.0250 (9)
C112	0.7775 (2)	0.2167 (4)	0.7294 (2)	0.0315 (11)
H112	0.7789	0.1545	0.7075	0.038*
C113	0.7237 (2)	0.2400 (4)	0.7426 (2)	0.0369 (12)
H113	0.6880	0.1939	0.7303	0.044*
C114	0.7217 (2)	0.3316 (4)	0.7742 (2)	0.0378 (13)
H114	0.6843	0.3485	0.7831	0.045*
C115	0.7742 (2)	0.3985 (4)	0.7928 (2)	0.0319 (11)
H115	0.7721	0.4611	0.8141	0.038*
C116	0.8297 (2)	0.3747 (4)	0.78066 (19)	0.0261 (10)
C117	0.8865 (2)	0.4436 (4)	0.80573 (19)	0.0251 (9)
H117	0.8784	0.5020	0.8306	0.030*
C118	0.9506 (2)	0.4014 (4)	0.83173 (19)	0.0222 (9)
H118	0.9756	0.4372	0.8701	0.027*
C119	0.96741 (18)	0.2888 (4)	0.83110 (17)	0.0225 (8)
C120	1.0153 (2)	0.2469 (4)	0.8813 (2)	0.0305 (10)
H120	1.0356	0.2914	0.9146	0.037*
C121	1.0336 (2)	0.1427 (4)	0.8834 (2)	0.0355 (11)
H121	1.0662	0.1165	0.9178	0.043*
C122	1.0046 (2)	0.0765 (4)	0.8357 (2)	0.0377 (12)
H122	1.0172	0.0047	0.8375	0.045*
C123	0.9566 (2)	0.1147 (4)	0.7848 (2)	0.0329 (11)
H123	0.9369	0.0700	0.7515	0.039*
C124	0.9384 (2)	0.2201 (4)	0.7839 (2)	0.0258 (10)
C125	0.9915 (2)	0.7609 (4)	0.7252 (2)	0.0252 (10)
C126	1.0323 (2)	0.8438 (4)	0.7271 (2)	0.0304 (10)
H126	1.0435	0.8921	0.7597	0.036*
C127	1.0570 (3)	0.8557 (4)	0.6807 (3)	0.0426 (13)
H127	1.0854	0.9121	0.6817	0.051*
C128	1.0405 (3)	0.7863 (5)	0.6339 (2)	0.0457 (13)
H128	1.0566	0.7956	0.6018	0.055*
C129	0.9998 (3)	0.7013 (4)	0.6328 (2)	0.0388 (12)
H129	0.9895	0.6523	0.6006	0.047*
C130	0.9742 (2)	0.6882 (4)	0.6788 (2)	0.0277 (10)
C131	0.9301 (2)	0.5980 (3)	0.67465 (19)	0.0237 (9)
H131	0.9218	0.5569	0.6367	0.028*
C132	0.8744 (2)	0.6037 (3)	0.69314 (19)	0.0256 (10)
H132	0.8372	0.5651	0.6649	0.031*
C133	0.8545 (2)	0.7011 (4)	0.71684 (19)	0.0230 (9)
C134	0.7897 (2)	0.7257 (4)	0.6996 (2)	0.0335 (11)
H134	0.7592	0.6766	0.6762	0.040*
C135	0.7687 (2)	0.8200 (4)	0.7157 (2)	0.0337 (12)
H135	0.7244	0.8357	0.7027	0.040*
C136	0.8123 (2)	0.8911 (4)	0.7507 (2)	0.0312 (11)
H136	0.7981	0.9564	0.7613	0.037*
C137	0.8768 (2)	0.8672 (3)	0.77056 (19)	0.0265 (10)
H137	0.9068	0.9154	0.7955	0.032*
C138	0.89738 (19)	0.7731 (3)	0.75402 (18)	0.0218 (9)
C141	0.2930 (3)	0.8346 (7)	0.8407 (4)	0.097 (3)
H141	0.3323	0.8373	0.8333	0.117*
C142	0.2839 (3)	0.8931 (7)	0.8859 (4)	0.096 (3)
H142	0.3167	0.9390	0.9090	0.115*
C143	0.2277 (3)	0.8862 (6)	0.8983 (3)	0.085 (3)
H143	0.2234	0.9256	0.9308	0.101*
C144	0.1775 (3)	0.8235 (5)	0.8646 (3)	0.072 (2)
H144	0.1386	0.8202	0.8728	0.086*
C145	0.1863 (3)	0.7664 (5)	0.8188 (3)	0.072 (2)
H145	0.1527	0.7224	0.7951	0.086*
C146	0.2430 (3)	0.7708 (5)	0.8059 (4)	0.082 (2)
H146	0.2476	0.7308	0.7737	0.098*
C151	0.2611 (5)	0.2053 (9)	0.1325 (5)	0.131 (3)
H151	0.2232	0.2269	0.1392	0.158*
C152	0.3172 (6)	0.1923 (11)	0.1794 (4)	0.145 (4)
H152	0.3180	0.2044	0.2193	0.174*
C153	0.3725 (5)	0.1619 (12)	0.1698 (5)	0.164 (4)
H153	0.4101	0.1518	0.2035	0.197*
C154	0.3752 (5)	0.1457 (11)	0.1128 (6)	0.160 (4)
H154	0.4141	0.1303	0.1062	0.192*
C155	0.3181 (6)	0.1533 (10)	0.0662 (5)	0.152 (4)
H155	0.3170	0.1359	0.0268	0.183*
C156	0.2618 (5)	0.1854 (10)	0.0746 (5)	0.154 (4)
H156	0.2239	0.1938	0.0410	0.185*
C161	0.1058 (5)	0.1464 (8)	0.7364 (4)	0.115 (4)
H158	0.0888	0.2002	0.7565	0.173*
H159	0.0725	0.0946	0.7174	0.173*
H160	0.1199	0.1799	0.7057	0.173*
C162	0.1616 (4)	0.0921 (6)	0.7817 (5)	0.118 (4)
H161	0.1465	0.0529	0.8105	0.141*
H162	0.1803	0.0407	0.7609	0.141*
C163	0.2115 (4)	0.1692 (7)	0.8150 (4)	0.112 (3)
H163	0.2219	0.2156	0.7859	0.135*
H164	0.2508	0.1307	0.8382	0.135*
C164	0.1894 (5)	0.2353 (7)	0.8571 (4)	0.102 (3)
H165	0.1428	0.2455	0.8387	0.122*
H166	0.2096	0.3055	0.8603	0.122*
C165	0.2031 (6)	0.1928 (10)	0.9198 (5)	0.177 (7)
H167	0.2421	0.2254	0.9469	0.265*
H168	0.2089	0.1163	0.9196	0.265*
H169	0.1672	0.2091	0.9335	0.265*
C171	0.1116 (5)	0.5245 (7)	0.3785 (4)	0.119 (3)
H171	0.0948	0.5927	0.3857	0.179*
H172	0.0789	0.4874	0.3462	0.179*
H173	0.1494	0.5358	0.3669	0.179*
C172	0.1296 (7)	0.4593 (10)	0.4352 (4)	0.173 (4)
H174	0.1508	0.5048	0.4702	0.208*
H175	0.0906	0.4300	0.4402	0.208*
C173	0.1734 (7)	0.3711 (10)	0.4332 (5)	0.191 (5)
H176	0.2056	0.3969	0.4161	0.229*
H177	0.1487	0.3142	0.4069	0.229*
C174	0.2067 (6)	0.3280 (10)	0.4956 (6)	0.185 (5)
H178	0.2469	0.2941	0.4960	0.222*
H179	0.2184	0.3881	0.5238	0.222*
C175	0.1700 (6)	0.2496 (10)	0.5191 (6)	0.158 (4)
H180	0.1317	0.2834	0.5223	0.237*
H181	0.1970	0.2249	0.5588	0.237*
H182	0.1576	0.1896	0.4916	0.237*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ir1	0.01763 (8)	0.02306 (9)	0.02088 (8)	−0.00031 (7)	0.00400 (6)	−0.00161 (7)
Cl1	0.0209 (5)	0.0472 (7)	0.0281 (6)	0.0076 (5)	0.0063 (5)	0.0028 (5)
P1	0.0186 (5)	0.0275 (6)	0.0220 (6)	−0.0015 (5)	0.0032 (5)	0.0013 (5)
P2	0.0206 (5)	0.0223 (6)	0.0206 (5)	−0.0001 (5)	0.0049 (4)	−0.0021 (5)
O1	0.0180 (15)	0.0339 (18)	0.0279 (16)	−0.0009 (13)	0.0005 (13)	0.0031 (14)
O2	0.0225 (14)	0.0370 (19)	0.0210 (14)	0.0044 (14)	0.0035 (12)	0.0015 (14)
O3	0.0213 (14)	0.0257 (16)	0.0225 (15)	−0.0014 (12)	0.0062 (12)	−0.0032 (13)
O4	0.0212 (14)	0.0263 (16)	0.0210 (15)	0.0031 (12)	0.0023 (12)	0.0005 (13)
N1	0.0201 (17)	0.029 (2)	0.0268 (18)	−0.0039 (17)	0.0034 (14)	0.0013 (18)
N2	0.0230 (19)	0.0220 (19)	0.030 (2)	0.0001 (15)	0.0088 (16)	−0.0019 (16)
C1	0.019 (2)	0.039 (3)	0.025 (2)	−0.0018 (19)	−0.0013 (18)	0.007 (2)
C2	0.026 (2)	0.034 (3)	0.025 (2)	−0.0051 (19)	0.0057 (19)	0.0054 (19)
C3	0.023 (2)	0.039 (3)	0.025 (2)	−0.0061 (19)	0.0023 (19)	0.009 (2)
C4	0.033 (3)	0.044 (3)	0.031 (3)	−0.006 (2)	0.006 (2)	0.005 (2)
C5	0.039 (3)	0.046 (3)	0.040 (3)	−0.012 (2)	0.007 (3)	−0.007 (3)
C6	0.036 (3)	0.051 (4)	0.054 (4)	−0.016 (3)	0.001 (3)	−0.006 (3)
C7	0.028 (3)	0.050 (3)	0.053 (3)	−0.012 (2)	0.009 (2)	−0.002 (3)
C8	0.024 (2)	0.040 (3)	0.032 (3)	−0.008 (2)	0.002 (2)	0.009 (2)
C9	0.019 (2)	0.051 (3)	0.034 (2)	−0.008 (3)	0.0053 (19)	0.003 (3)
C10	0.022 (2)	0.051 (3)	0.026 (2)	−0.002 (2)	0.004 (2)	0.003 (2)
C11	0.031 (2)	0.037 (3)	0.021 (2)	−0.007 (2)	0.0091 (19)	−0.001 (2)
C12	0.024 (2)	0.036 (3)	0.024 (2)	−0.006 (2)	0.0053 (19)	0.004 (2)
C13	0.035 (3)	0.040 (3)	0.025 (2)	−0.011 (2)	0.006 (2)	0.001 (2)
C14	0.037 (3)	0.053 (4)	0.036 (3)	−0.012 (3)	0.004 (2)	0.013 (3)
C15	0.056 (4)	0.067 (4)	0.035 (3)	−0.012 (3)	0.003 (3)	0.025 (3)
C16	0.074 (5)	0.087 (5)	0.035 (3)	−0.025 (4)	0.013 (3)	0.017 (3)
C17	0.054 (4)	0.088 (5)	0.035 (3)	−0.020 (3)	0.017 (3)	0.008 (3)
C18	0.045 (3)	0.052 (3)	0.030 (3)	−0.018 (3)	0.013 (2)	−0.001 (3)
C19	0.030 (3)	0.066 (4)	0.035 (3)	−0.007 (3)	0.016 (2)	−0.004 (3)
C20	0.027 (2)	0.047 (3)	0.033 (3)	−0.003 (2)	0.011 (2)	−0.006 (2)
C21	0.023 (2)	0.024 (2)	0.022 (2)	−0.0033 (19)	0.0086 (17)	−0.0031 (19)
C22	0.022 (2)	0.025 (2)	0.021 (2)	0.0010 (19)	0.0080 (17)	−0.0004 (19)
C23	0.026 (2)	0.023 (2)	0.023 (2)	0.0031 (18)	0.0105 (19)	0.0020 (18)
C24	0.030 (2)	0.022 (2)	0.030 (2)	−0.0032 (19)	0.011 (2)	0.0018 (19)
C25	0.040 (3)	0.033 (3)	0.034 (3)	−0.013 (2)	0.015 (2)	−0.009 (2)
C26	0.056 (3)	0.019 (2)	0.048 (3)	−0.004 (2)	0.030 (3)	−0.008 (2)
C27	0.046 (3)	0.026 (2)	0.038 (3)	0.009 (2)	0.019 (2)	0.001 (2)
C28	0.036 (2)	0.023 (2)	0.030 (2)	0.004 (2)	0.0166 (19)	0.001 (2)
C29	0.034 (2)	0.035 (3)	0.031 (2)	0.014 (2)	0.011 (2)	0.004 (2)
C30	0.032 (2)	0.037 (3)	0.020 (2)	0.011 (2)	0.0098 (19)	0.004 (2)
C31	0.022 (2)	0.024 (2)	0.022 (2)	0.0008 (17)	0.0035 (18)	−0.0006 (18)
C32	0.0164 (19)	0.021 (2)	0.022 (2)	−0.0031 (17)	0.0017 (17)	−0.0037 (18)
C33	0.024 (2)	0.021 (2)	0.025 (2)	−0.0046 (18)	0.0040 (19)	−0.0013 (18)
C34	0.026 (2)	0.028 (2)	0.025 (2)	−0.004 (2)	0.0046 (19)	−0.001 (2)
C35	0.032 (3)	0.040 (3)	0.028 (2)	−0.007 (2)	0.008 (2)	0.000 (2)
C36	0.036 (3)	0.040 (3)	0.027 (2)	−0.009 (2)	0.004 (2)	0.009 (2)
C37	0.029 (2)	0.021 (3)	0.039 (3)	−0.0019 (18)	0.000 (2)	0.004 (2)
C38	0.025 (2)	0.023 (2)	0.026 (2)	−0.0002 (18)	−0.0012 (19)	−0.0013 (19)
C39	0.032 (2)	0.025 (2)	0.028 (2)	0.0051 (19)	−0.002 (2)	−0.0024 (19)
C40	0.028 (2)	0.027 (2)	0.034 (3)	0.007 (2)	0.005 (2)	−0.006 (2)
C41	0.017 (2)	0.025 (2)	0.044 (3)	−0.0003 (18)	0.007 (2)	−0.002 (2)
C42	0.036 (3)	0.039 (3)	0.042 (3)	−0.005 (2)	0.008 (2)	0.007 (2)
C43	0.039 (3)	0.034 (3)	0.080 (5)	−0.006 (2)	0.014 (3)	−0.017 (3)
C44	0.037 (3)	0.033 (3)	0.059 (4)	0.001 (2)	0.012 (3)	−0.005 (3)
C45	0.024 (2)	0.034 (3)	0.040 (3)	−0.006 (2)	0.009 (2)	−0.014 (2)
C46	0.016 (2)	0.020 (2)	0.039 (3)	−0.0035 (17)	0.003 (2)	−0.0016 (19)
C47	0.021 (2)	0.023 (2)	0.021 (2)	0.0002 (18)	0.0033 (18)	−0.0060 (18)
C48	0.017 (2)	0.024 (2)	0.027 (2)	−0.0050 (17)	0.0017 (18)	−0.0023 (19)
C49	0.019 (2)	0.030 (2)	0.026 (2)	−0.0007 (18)	0.0036 (18)	−0.0067 (19)
C50	0.025 (2)	0.048 (3)	0.030 (3)	0.005 (2)	0.008 (2)	0.000 (2)
C51	0.021 (2)	0.062 (4)	0.047 (3)	0.004 (2)	0.007 (2)	−0.007 (3)
C52	0.026 (2)	0.071 (4)	0.042 (3)	−0.009 (3)	0.012 (2)	−0.002 (3)
C53	0.032 (2)	0.052 (3)	0.032 (2)	−0.010 (3)	0.013 (2)	0.003 (3)
C54	0.020 (2)	0.034 (3)	0.026 (2)	−0.0028 (18)	0.0025 (18)	−0.0061 (19)
C55	0.025 (2)	0.028 (3)	0.027 (2)	−0.0014 (18)	0.0046 (19)	−0.0060 (19)
C56	0.038 (3)	0.022 (2)	0.034 (3)	−0.002 (2)	0.008 (2)	−0.002 (2)
C57	0.042 (3)	0.030 (3)	0.045 (3)	0.016 (2)	0.008 (2)	−0.003 (2)
C58	0.035 (3)	0.043 (3)	0.051 (3)	0.015 (2)	0.013 (3)	−0.003 (3)
C59	0.034 (3)	0.043 (3)	0.040 (3)	0.007 (2)	0.015 (2)	0.000 (2)
C60	0.023 (2)	0.024 (2)	0.033 (3)	0.0054 (18)	0.007 (2)	−0.005 (2)
C61	0.029 (2)	0.025 (2)	0.022 (2)	−0.0018 (19)	0.0070 (19)	−0.0003 (19)
C62	0.027 (2)	0.024 (2)	0.019 (2)	−0.0011 (19)	0.0046 (18)	−0.0063 (18)
C63	0.026 (2)	0.027 (2)	0.032 (3)	−0.001 (2)	0.009 (2)	−0.009 (2)
C64	0.030 (3)	0.034 (3)	0.036 (3)	−0.003 (2)	0.008 (2)	−0.008 (2)
C65	0.025 (2)	0.053 (3)	0.053 (3)	−0.010 (3)	0.009 (2)	−0.016 (3)
C66	0.034 (3)	0.036 (3)	0.056 (3)	−0.014 (2)	0.021 (3)	−0.008 (3)
C67	0.036 (3)	0.032 (3)	0.039 (3)	−0.002 (2)	0.020 (2)	−0.005 (2)
C68	0.029 (2)	0.023 (2)	0.034 (3)	−0.0019 (19)	0.014 (2)	−0.008 (2)
Ir2	0.01930 (8)	0.01771 (8)	0.01886 (8)	−0.00251 (7)	0.00429 (6)	−0.00159 (7)
Cl2	0.0207 (5)	0.0502 (7)	0.0381 (7)	−0.0022 (5)	0.0073 (5)	−0.0207 (6)
P3	0.0192 (5)	0.0183 (6)	0.0201 (5)	−0.0023 (4)	0.0035 (5)	−0.0019 (4)
P4	0.0193 (5)	0.0188 (5)	0.0177 (5)	−0.0030 (4)	0.0047 (4)	−0.0012 (4)
O5	0.0204 (14)	0.0210 (15)	0.0178 (14)	0.0013 (12)	0.0007 (12)	−0.0044 (12)
O6	0.0197 (13)	0.0248 (15)	0.0219 (14)	−0.0010 (14)	0.0038 (11)	−0.0024 (14)
O7	0.0198 (14)	0.0188 (14)	0.0204 (14)	−0.0030 (12)	0.0054 (12)	−0.0028 (12)
O8	0.0174 (14)	0.0240 (15)	0.0197 (14)	−0.0051 (12)	0.0024 (12)	−0.0024 (12)
N3	0.0204 (18)	0.0205 (19)	0.0209 (18)	−0.0045 (14)	0.0023 (15)	−0.0005 (15)
N4	0.0199 (17)	0.0171 (17)	0.0217 (18)	−0.0072 (14)	0.0064 (15)	−0.0019 (14)
C71	0.020 (2)	0.019 (2)	0.022 (2)	0.0002 (17)	0.0001 (17)	0.0007 (17)
C72	0.0196 (19)	0.019 (2)	0.022 (2)	−0.0023 (18)	0.0016 (16)	−0.0011 (18)
C73	0.023 (2)	0.021 (2)	0.023 (2)	0.0011 (17)	0.0048 (18)	−0.0005 (18)
C74	0.032 (2)	0.026 (2)	0.024 (2)	−0.003 (2)	0.0023 (19)	−0.008 (2)
C75	0.049 (3)	0.036 (3)	0.030 (3)	0.005 (2)	0.010 (2)	−0.007 (2)
C76	0.049 (3)	0.032 (3)	0.034 (3)	−0.007 (2)	0.001 (2)	−0.017 (2)
C77	0.035 (3)	0.033 (3)	0.036 (3)	−0.010 (2)	0.004 (2)	−0.007 (2)
C78	0.030 (2)	0.022 (2)	0.023 (2)	−0.0048 (19)	0.0004 (19)	−0.0019 (19)
C79	0.021 (2)	0.030 (2)	0.031 (2)	−0.0057 (19)	0.0029 (19)	0.000 (2)
C80	0.024 (2)	0.028 (3)	0.024 (2)	−0.0018 (18)	0.0075 (18)	0.0027 (18)
C81	0.026 (2)	0.022 (2)	0.030 (2)	−0.0040 (18)	0.012 (2)	−0.0063 (19)
C82	0.025 (2)	0.021 (2)	0.023 (2)	−0.0022 (18)	0.0101 (18)	−0.0075 (18)
C83	0.036 (3)	0.027 (3)	0.027 (2)	−0.006 (2)	0.015 (2)	−0.007 (2)
C84	0.044 (3)	0.033 (3)	0.030 (3)	−0.007 (2)	0.014 (2)	−0.003 (2)
C85	0.063 (4)	0.040 (3)	0.034 (3)	−0.005 (3)	0.019 (3)	0.007 (2)
C86	0.079 (4)	0.048 (4)	0.040 (3)	−0.021 (3)	0.029 (3)	0.003 (3)
C87	0.058 (3)	0.055 (4)	0.043 (3)	−0.031 (3)	0.027 (3)	−0.012 (3)
C88	0.040 (3)	0.041 (3)	0.030 (3)	−0.016 (2)	0.017 (2)	−0.014 (2)
C89	0.030 (3)	0.055 (4)	0.041 (3)	−0.017 (2)	0.020 (2)	−0.018 (3)
C90	0.018 (2)	0.045 (3)	0.033 (3)	−0.006 (2)	0.007 (2)	−0.013 (2)
C91	0.028 (2)	0.022 (2)	0.017 (2)	−0.0068 (18)	0.0078 (18)	−0.0026 (17)
C92	0.024 (2)	0.022 (2)	0.022 (2)	−0.0040 (18)	0.0105 (18)	−0.0003 (18)
C93	0.031 (2)	0.022 (2)	0.020 (2)	−0.0023 (18)	0.0095 (19)	−0.0016 (18)
C94	0.026 (2)	0.029 (2)	0.023 (2)	−0.0074 (19)	0.0052 (19)	−0.0032 (19)
C95	0.033 (3)	0.031 (2)	0.029 (2)	−0.011 (2)	0.005 (2)	−0.006 (2)
C96	0.048 (3)	0.023 (3)	0.029 (2)	−0.003 (2)	0.011 (2)	−0.0103 (19)
C97	0.039 (2)	0.026 (2)	0.028 (2)	0.001 (2)	0.008 (2)	−0.007 (2)
C98	0.036 (2)	0.021 (2)	0.024 (2)	0.0000 (19)	0.011 (2)	−0.0015 (19)
C99	0.028 (2)	0.026 (2)	0.027 (2)	0.0055 (19)	0.009 (2)	0.001 (2)
C100	0.024 (2)	0.027 (3)	0.024 (2)	0.0026 (18)	0.0078 (18)	0.0020 (19)
C101	0.017 (2)	0.022 (2)	0.017 (2)	−0.0030 (16)	0.0017 (16)	−0.0001 (17)
C102	0.020 (2)	0.018 (2)	0.024 (2)	−0.0031 (17)	0.0032 (17)	−0.0017 (18)
C103	0.020 (2)	0.023 (2)	0.024 (2)	−0.0048 (17)	0.0027 (18)	−0.0020 (18)
C104	0.027 (2)	0.028 (2)	0.024 (2)	−0.0010 (19)	0.0045 (19)	−0.002 (2)
C105	0.036 (3)	0.046 (3)	0.026 (2)	−0.005 (2)	0.004 (2)	0.001 (2)
C106	0.028 (2)	0.056 (4)	0.030 (3)	0.005 (2)	−0.001 (2)	0.017 (2)
C107	0.025 (2)	0.043 (3)	0.038 (3)	0.008 (2)	0.006 (2)	0.009 (2)
C108	0.019 (2)	0.028 (3)	0.029 (2)	0.0007 (17)	0.0045 (18)	0.0054 (19)
C109	0.023 (2)	0.028 (3)	0.041 (3)	0.004 (2)	0.010 (2)	0.003 (2)
C110	0.022 (2)	0.028 (3)	0.031 (2)	−0.0009 (18)	0.0089 (19)	−0.0061 (19)
C111	0.0195 (19)	0.031 (2)	0.022 (2)	−0.001 (2)	0.0033 (16)	0.004 (2)
C112	0.030 (2)	0.033 (3)	0.027 (2)	−0.009 (2)	0.002 (2)	0.005 (2)
C113	0.026 (2)	0.047 (3)	0.030 (3)	−0.014 (2)	−0.001 (2)	0.009 (2)
C114	0.020 (2)	0.056 (3)	0.037 (3)	−0.006 (2)	0.010 (2)	0.014 (3)
C115	0.031 (2)	0.037 (3)	0.027 (2)	0.001 (2)	0.008 (2)	0.006 (2)
C116	0.023 (2)	0.031 (2)	0.024 (2)	−0.0041 (19)	0.0078 (18)	0.0071 (19)
C117	0.025 (2)	0.024 (2)	0.026 (2)	0.0002 (19)	0.0077 (19)	0.0016 (19)
C118	0.019 (2)	0.026 (2)	0.019 (2)	−0.0048 (18)	0.0027 (18)	−0.0019 (18)
C119	0.024 (2)	0.023 (2)	0.0181 (19)	−0.001 (2)	0.0039 (16)	0.003 (2)
C120	0.029 (2)	0.030 (2)	0.026 (2)	−0.003 (2)	0.002 (2)	0.001 (2)
C121	0.034 (3)	0.034 (3)	0.033 (3)	0.003 (2)	0.004 (2)	0.011 (2)
C122	0.045 (3)	0.023 (2)	0.040 (3)	0.004 (2)	0.008 (2)	0.010 (2)
C123	0.036 (3)	0.020 (2)	0.042 (3)	−0.001 (2)	0.013 (2)	0.009 (2)
C124	0.026 (2)	0.024 (2)	0.023 (2)	−0.0023 (19)	0.0031 (19)	0.0025 (19)
C125	0.026 (2)	0.027 (3)	0.023 (2)	0.0033 (18)	0.0081 (19)	0.0032 (18)
C126	0.036 (3)	0.025 (2)	0.034 (3)	−0.005 (2)	0.016 (2)	−0.002 (2)
C127	0.044 (3)	0.038 (3)	0.054 (3)	−0.011 (2)	0.027 (3)	0.003 (3)
C128	0.061 (3)	0.043 (3)	0.049 (3)	−0.001 (3)	0.039 (3)	0.006 (3)
C129	0.056 (3)	0.030 (3)	0.038 (3)	−0.004 (2)	0.026 (3)	0.001 (2)
C130	0.036 (3)	0.021 (2)	0.027 (2)	0.0014 (19)	0.013 (2)	0.0037 (19)
C131	0.034 (2)	0.017 (2)	0.017 (2)	0.0014 (19)	0.0054 (19)	0.0014 (18)
C132	0.029 (2)	0.020 (2)	0.021 (2)	0.0030 (18)	−0.0002 (19)	−0.0019 (18)
C133	0.023 (2)	0.022 (2)	0.022 (2)	−0.0011 (18)	0.0043 (18)	0.0022 (19)
C134	0.025 (2)	0.030 (3)	0.037 (3)	0.000 (2)	0.000 (2)	0.003 (2)
C135	0.027 (2)	0.036 (3)	0.034 (3)	0.003 (2)	0.005 (2)	0.001 (2)
C136	0.037 (3)	0.025 (2)	0.031 (3)	0.009 (2)	0.009 (2)	0.003 (2)
C137	0.033 (2)	0.020 (2)	0.023 (2)	−0.0012 (19)	0.0042 (19)	0.0010 (18)
C138	0.023 (2)	0.022 (2)	0.020 (2)	−0.0020 (18)	0.0060 (17)	0.0024 (18)
C141	0.055 (5)	0.093 (7)	0.143 (9)	0.001 (4)	0.032 (5)	0.029 (6)
C142	0.050 (5)	0.098 (7)	0.117 (8)	−0.020 (5)	0.000 (5)	0.026 (6)
C143	0.062 (5)	0.090 (6)	0.088 (6)	−0.015 (4)	0.008 (4)	0.033 (5)
C144	0.062 (4)	0.061 (5)	0.090 (5)	−0.009 (3)	0.023 (4)	0.021 (4)
C145	0.055 (4)	0.061 (5)	0.101 (6)	−0.003 (3)	0.027 (4)	0.025 (4)
C146	0.071 (5)	0.058 (5)	0.111 (6)	0.003 (4)	0.024 (5)	0.035 (5)
C151	0.161 (8)	0.085 (5)	0.131 (7)	0.007 (6)	0.027 (6)	−0.011 (6)
C152	0.162 (8)	0.125 (7)	0.129 (7)	0.008 (7)	0.025 (7)	0.000 (6)
C153	0.191 (9)	0.141 (7)	0.146 (7)	0.001 (7)	0.037 (7)	−0.005 (7)
C154	0.202 (9)	0.109 (6)	0.146 (8)	−0.009 (7)	0.030 (7)	0.006 (7)
C155	0.197 (9)	0.102 (6)	0.153 (7)	−0.007 (7)	0.054 (7)	0.006 (6)
C156	0.186 (8)	0.102 (6)	0.156 (7)	−0.002 (7)	0.035 (7)	0.000 (7)
C161	0.139 (9)	0.074 (6)	0.114 (8)	−0.009 (6)	0.018 (7)	0.001 (6)
C162	0.148 (10)	0.074 (6)	0.148 (10)	−0.018 (7)	0.071 (8)	−0.013 (7)
C163	0.096 (7)	0.090 (7)	0.156 (10)	−0.027 (6)	0.051 (7)	−0.030 (7)
C164	0.119 (8)	0.091 (7)	0.106 (7)	−0.015 (6)	0.053 (7)	−0.008 (6)
C165	0.125 (10)	0.104 (9)	0.245 (18)	−0.018 (8)	−0.011 (11)	0.040 (11)
C171	0.185 (9)	0.091 (7)	0.073 (5)	−0.014 (6)	0.031 (6)	0.019 (5)
C172	0.210 (9)	0.134 (8)	0.140 (7)	0.013 (7)	0.014 (7)	0.014 (7)
C173	0.190 (9)	0.175 (9)	0.176 (9)	0.034 (7)	0.021 (8)	0.013 (8)
C174	0.181 (9)	0.148 (9)	0.210 (10)	0.036 (7)	0.046 (8)	0.030 (8)
C175	0.162 (10)	0.123 (9)	0.200 (11)	0.019 (7)	0.075 (8)	0.025 (8)

Geometric parameters (Å, º)

Ir1—P1	2.2756 (12)	C74—H74	0.9500
Ir1—P2	2.2676 (11)	C75—C76	1.412 (8)
Ir1—Cl1	2.4512 (11)	C75—H75	0.9500
Ir1—C47	2.184 (4)	C76—C77	1.359 (8)
Ir1—C48	2.189 (4)	C76—H76	0.9500
Ir1—C61	2.189 (5)	C77—C78	1.414 (7)
Ir1—C62	2.185 (4)	C77—H77	0.9500
P1—O2	1.604 (3)	C78—C79	1.424 (7)
P1—O1	1.605 (3)	C79—C80	1.358 (6)
P1—N1	1.688 (4)	C79—H79	0.9500
P2—O3	1.605 (3)	C80—H80	0.9500
P2—O4	1.610 (3)	C81—C82	1.377 (6)
P2—N2	1.690 (4)	C81—C90	1.399 (6)
O1—C1	1.419 (5)	C82—C83	1.432 (6)
O2—C11	1.407 (5)	C83—C84	1.423 (7)
O3—C21	1.411 (5)	C83—C88	1.433 (7)
O4—C31	1.404 (5)	C84—C85	1.363 (7)
N1—C41	1.456 (6)	C84—H84	0.9500
N1—C54	1.461 (5)	C85—C86	1.401 (8)
N2—C55	1.453 (6)	C85—H85	0.9500
N2—C68	1.454 (6)	C86—C87	1.350 (9)
C1—C2	1.367 (7)	C86—H86	0.9500
C1—C10	1.408 (7)	C87—C88	1.408 (7)
C2—C3	1.437 (6)	C87—H87	0.9500
C2—C12	1.495 (6)	C88—C89	1.418 (8)
C3—C8	1.418 (7)	C89—C90	1.358 (7)
C3—C4	1.427 (7)	C89—H89	0.9500
C4—C5	1.355 (7)	C90—H90	0.9500
C4—H4	0.9500	C91—C92	1.380 (6)
C5—C6	1.414 (8)	C91—C100	1.397 (6)
C5—H5	0.9500	C92—C93	1.455 (6)
C6—C7	1.371 (8)	C92—C102	1.486 (6)
C6—H6	0.9500	C93—C98	1.413 (6)
C7—C8	1.410 (7)	C93—C94	1.417 (6)
C7—H7	0.9500	C94—C95	1.367 (7)
C8—C9	1.424 (8)	C94—H94	0.9500
C9—C10	1.367 (7)	C95—C96	1.395 (7)
C9—H9	0.9500	C95—H95	0.9500
C10—H10	0.9500	C96—C97	1.365 (7)
C11—C12	1.370 (6)	C96—H96	0.9500
C11—C20	1.392 (7)	C97—C98	1.422 (7)
C12—C13	1.438 (7)	C97—H97	0.9500
C13—C14	1.415 (7)	C98—C99	1.423 (6)
C13—C18	1.418 (7)	C99—C100	1.356 (7)
C14—C15	1.368 (8)	C99—H99	0.9500
C14—H14	0.9500	C100—H100	0.9500
C15—C16	1.413 (9)	C101—C102	1.365 (6)
C15—H15	0.9500	C101—C110	1.411 (6)
C16—C17	1.360 (9)	C102—C103	1.442 (6)
C16—H16	0.9500	C103—C104	1.423 (6)
C17—C18	1.407 (8)	C103—C108	1.425 (6)
C17—H17	0.9500	C104—C105	1.364 (7)
C18—C19	1.422 (8)	C104—H104	0.9500
C19—C20	1.366 (7)	C105—C106	1.399 (8)
C19—H19	0.9500	C105—H105	0.9500
C20—H20	0.9500	C106—C107	1.377 (7)
C21—C22	1.377 (6)	C106—H106	0.9500
C21—C30	1.398 (6)	C107—C108	1.419 (6)
C22—C23	1.445 (6)	C107—H107	0.9500
C22—C32	1.477 (6)	C108—C109	1.413 (7)
C23—C24	1.397 (6)	C109—C110	1.358 (7)
C23—C28	1.426 (6)	C109—H109	0.9500
C24—C25	1.369 (7)	C110—H110	0.9500
C24—H24	0.9500	C111—C112	1.394 (6)
C25—C26	1.407 (7)	C111—C116	1.397 (7)
C25—H25	0.9500	C112—C113	1.369 (7)
C26—C27	1.372 (7)	C112—H112	0.9500
C26—H26	0.9500	C113—C114	1.391 (8)
C27—C28	1.414 (7)	C113—H113	0.9500
C27—H27	0.9500	C114—C115	1.390 (7)
C28—C29	1.420 (6)	C114—H114	0.9500
C29—C30	1.361 (7)	C115—C116	1.394 (6)
C29—H29	0.9500	C115—H115	0.9500
C30—H30	0.9500	C116—C117	1.488 (6)
C31—C32	1.373 (6)	C117—C118	1.453 (6)
C31—C40	1.410 (6)	C117—H117	1.0000
C32—C33	1.441 (6)	C118—C119	1.479 (7)
C33—C34	1.418 (6)	C118—H118	1.0000
C33—C38	1.434 (6)	C119—C124	1.392 (6)
C34—C35	1.374 (7)	C119—C120	1.406 (6)
C34—H34	0.9500	C120—C121	1.380 (7)
C35—C36	1.390 (7)	C120—H120	0.9500
C35—H35	0.9500	C121—C122	1.381 (7)
C36—C37	1.361 (7)	C121—H121	0.9500
C36—H36	0.9500	C122—C123	1.400 (7)
C37—C38	1.422 (7)	C122—H122	0.9500
C37—H37	0.9500	C123—C124	1.396 (7)
C38—C39	1.404 (7)	C123—H123	0.9500
C39—C40	1.375 (7)	C125—C126	1.381 (6)
C39—H39	0.9500	C125—C130	1.385 (7)
C40—H40	0.9500	C126—C127	1.391 (7)
C41—C42	1.398 (7)	C126—H126	0.9500
C41—C46	1.398 (7)	C127—C128	1.367 (8)
C42—C43	1.371 (8)	C127—H127	0.9500
C42—H42	0.9500	C128—C129	1.404 (8)
C43—C44	1.375 (9)	C128—H128	0.9500
C43—H43	0.9500	C129—C130	1.398 (7)
C44—C45	1.373 (8)	C129—H129	0.9500
C44—H44	0.9500	C130—C131	1.491 (6)
C45—C46	1.394 (7)	C131—C132	1.449 (6)
C45—H45	0.9500	C131—H131	1.0000
C46—C47	1.480 (6)	C132—C133	1.486 (6)
C47—C48	1.452 (6)	C132—H132	1.0000
C47—H47	1.0000	C133—C134	1.397 (6)
C48—C49	1.472 (6)	C133—C138	1.398 (6)
C48—H48	1.0000	C134—C135	1.385 (7)
C49—C50	1.402 (6)	C134—H134	0.9500
C49—C54	1.406 (7)	C135—C136	1.379 (7)
C50—C51	1.394 (7)	C135—H135	0.9500
C50—H50	0.9500	C136—C137	1.386 (7)
C51—C52	1.369 (8)	C136—H136	0.9500
C51—H51	0.9500	C137—C138	1.383 (6)
C52—C53	1.388 (7)	C137—H137	0.9500
C52—H52	0.9500	C141—C142	1.372 (6)
C53—C54	1.376 (6)	C141—C146	1.397 (6)
C53—H53	0.9500	C141—H141	0.9500
C55—C56	1.394 (7)	C142—C143	1.381 (6)
C55—C60	1.395 (7)	C142—H142	0.9500
C56—C57	1.387 (7)	C143—C144	1.385 (6)
C56—H56	0.9500	C143—H143	0.9500
C57—C58	1.389 (8)	C144—C145	1.371 (6)
C57—H57	0.9500	C144—H144	0.9500
C58—C59	1.392 (7)	C145—C146	1.398 (6)
C58—H58	0.9500	C145—H145	0.9500
C59—C60	1.404 (7)	C146—H146	0.9500
C59—H59	0.9500	C151—C152	1.372 (5)
C60—C61	1.486 (6)	C151—C156	1.400 (5)
C61—C62	1.447 (6)	C151—H151	0.9500
C61—H61	1.0000	C152—C153	1.381 (5)
C62—C63	1.481 (7)	C152—H152	0.9500
C62—H62	1.0000	C153—C154	1.387 (5)
C63—C68	1.396 (7)	C153—H153	0.9500
C63—C64	1.406 (6)	C154—C155	1.376 (5)
C64—C65	1.385 (8)	C154—H154	0.9500
C64—H64	0.9500	C155—C156	1.395 (5)
C65—C66	1.376 (8)	C155—H155	0.9500
C65—H65	0.9500	C156—H156	0.9500
C66—C67	1.377 (7)	C161—C162	1.506 (6)
C66—H66	0.9500	C161—H158	0.9800
C67—C68	1.395 (7)	C161—H159	0.9800
C67—H67	0.9500	C161—H160	0.9800
Ir2—P3	2.2790 (11)	C162—C163	1.491 (6)
Ir2—P4	2.2717 (11)	C162—H161	0.9900
Ir2—Cl2	2.4394 (11)	C162—H162	0.9900
Ir2—C117	2.187 (4)	C163—C164	1.507 (6)
Ir2—C118	2.192 (4)	C163—H163	0.9900
Ir2—C131	2.185 (4)	C163—H164	0.9900
Ir2—C132	2.187 (4)	C164—C165	1.510 (6)
P3—O6	1.610 (3)	C164—H165	0.9900
P3—O5	1.610 (3)	C164—H166	0.9900
P3—N3	1.689 (4)	C165—H167	0.9800
P4—O8	1.603 (3)	C165—H168	0.9800
P4—O7	1.610 (3)	C165—H169	0.9800
P4—N4	1.681 (4)	C171—C172	1.510 (4)
O5—C71	1.409 (5)	C171—H171	0.9800
O6—C81	1.417 (5)	C171—H172	0.9800
O7—C91	1.418 (5)	C171—H173	0.9800
O8—C101	1.407 (5)	C172—C173	1.496 (4)
N3—C111	1.453 (5)	C172—H174	0.9900
N3—C124	1.464 (6)	C172—H175	0.9900
N4—C138	1.458 (5)	C173—C174	1.513 (4)
N4—C125	1.474 (5)	C173—H176	0.9900
C71—C72	1.371 (6)	C173—H177	0.9900
C71—C80	1.415 (6)	C174—C175	1.509 (4)
C72—C73	1.433 (6)	C174—H178	0.9900
C72—C82	1.494 (6)	C174—H179	0.9900
C73—C74	1.423 (6)	C175—H180	0.9800
C73—C78	1.427 (6)	C175—H181	0.9800
C74—C75	1.365 (7)	C175—H182	0.9800
P2—Ir1—P1	175.06 (4)	C73—C72—C82	121.2 (4)
P1—Ir1—Cl1	91.85 (4)	C74—C73—C78	117.8 (4)
P2—Ir1—Cl1	93.08 (4)	C74—C73—C72	122.6 (4)
C47—Ir1—P1	87.93 (12)	C78—C73—C72	119.7 (4)
C48—Ir1—P1	85.86 (12)	C75—C74—C73	121.2 (5)
C61—Ir1—P1	90.91 (12)	C75—C74—H74	119.4
C62—Ir1—P1	91.81 (12)	C73—C74—H74	119.4
C47—Ir1—P2	92.35 (12)	C74—C75—C76	120.5 (5)
C48—Ir1—P2	91.26 (12)	C74—C75—H75	119.8
C61—Ir1—P2	85.66 (12)	C76—C75—H75	119.8
C62—Ir1—P2	87.74 (12)	C77—C76—C75	119.9 (4)
C47—Ir1—Cl1	91.47 (11)	C77—C76—H76	120.1
C48—Ir1—Cl1	130.22 (12)	C75—C76—H76	120.1
C61—Ir1—Cl1	129.17 (12)	C76—C77—C78	121.3 (5)
C62—Ir1—Cl1	90.53 (12)	C76—C77—H77	119.4
C47—Ir1—C48	38.78 (16)	C78—C77—H77	119.4
C47—Ir1—C61	139.35 (16)	C77—C78—C79	122.1 (4)
C47—Ir1—C62	177.99 (17)	C77—C78—C73	119.3 (4)
C48—Ir1—C61	100.60 (16)	C79—C78—C73	118.6 (4)
C48—Ir1—C62	139.21 (17)	C80—C79—C78	121.4 (4)
C61—Ir1—C62	38.65 (16)	C80—C79—H79	119.3
O2—P1—O1	104.47 (16)	C78—C79—H79	119.3
O2—P1—N1	105.21 (18)	C79—C80—C71	119.1 (4)
O1—P1—N1	97.73 (18)	C79—C80—H80	120.5
O2—P1—Ir1	110.90 (13)	C71—C80—H80	120.5
O1—P1—Ir1	123.63 (13)	C82—C81—C90	122.9 (4)
N1—P1—Ir1	112.87 (13)	C82—C81—O6	119.1 (4)
O3—P2—O4	103.68 (16)	C90—C81—O6	118.0 (4)
O3—P2—N2	98.81 (18)	C81—C82—C83	117.9 (4)
O4—P2—N2	103.87 (17)	C81—C82—C72	120.0 (4)
O3—P2—Ir1	121.70 (12)	C83—C82—C72	122.1 (4)
O4—P2—Ir1	113.46 (12)	C84—C83—C82	123.2 (4)
N2—P2—Ir1	113.01 (14)	C84—C83—C88	117.5 (4)
C1—O1—P1	117.6 (3)	C82—C83—C88	119.2 (4)
C11—O2—P1	123.4 (3)	C85—C84—C83	121.1 (5)
C21—O3—P2	116.5 (3)	C85—C84—H84	119.4
C31—O4—P2	120.3 (3)	C83—C84—H84	119.4
C41—N1—C54	112.4 (3)	C84—C85—C86	120.7 (5)
C41—N1—P1	111.7 (3)	C84—C85—H85	119.7
C54—N1—P1	112.3 (3)	C86—C85—H85	119.7
C55—N2—C68	112.0 (3)	C87—C86—C85	120.1 (5)
C55—N2—P2	112.4 (3)	C87—C86—H86	120.0
C68—N2—P2	112.6 (3)	C85—C86—H86	120.0
C2—C1—C10	123.7 (4)	C86—C87—C88	121.6 (5)
C2—C1—O1	118.8 (4)	C86—C87—H87	119.2
C10—C1—O1	117.4 (4)	C88—C87—H87	119.2
C1—C2—C3	117.8 (4)	C87—C88—C89	122.4 (5)
C1—C2—C12	121.1 (4)	C87—C88—C83	119.0 (5)
C3—C2—C12	121.0 (4)	C89—C88—C83	118.5 (4)
C8—C3—C4	118.1 (4)	C90—C89—C88	121.5 (4)
C8—C3—C2	119.2 (5)	C90—C89—H89	119.2
C4—C3—C2	122.7 (4)	C88—C89—H89	119.2
C5—C4—C3	121.2 (5)	C89—C90—C81	119.1 (5)
C5—C4—H4	119.4	C89—C90—H90	120.4
C3—C4—H4	119.4	C81—C90—H90	120.4
C4—C5—C6	120.3 (6)	C92—C91—C100	123.2 (4)
C4—C5—H5	119.8	C92—C91—O7	119.8 (4)
C6—C5—H5	119.8	C100—C91—O7	116.8 (4)
C7—C6—C5	120.1 (5)	C91—C92—C93	116.8 (4)
C7—C6—H6	120.0	C91—C92—C102	121.3 (4)
C5—C6—H6	120.0	C93—C92—C102	121.8 (4)
C6—C7—C8	120.7 (5)	C98—C93—C94	119.2 (4)
C6—C7—H7	119.7	C98—C93—C92	119.1 (4)
C8—C7—H7	119.7	C94—C93—C92	121.7 (4)
C7—C8—C3	119.4 (5)	C95—C94—C93	120.0 (4)
C7—C8—C9	121.1 (5)	C95—C94—H94	120.0
C3—C8—C9	119.5 (4)	C93—C94—H94	120.0
C10—C9—C8	120.9 (4)	C94—C95—C96	121.2 (4)
C10—C9—H9	119.6	C94—C95—H95	119.4
C8—C9—H9	119.6	C96—C95—H95	119.4
C9—C10—C1	118.5 (5)	C97—C96—C95	120.3 (4)
C9—C10—H10	120.7	C97—C96—H96	119.9
C1—C10—H10	120.7	C95—C96—H96	119.9
C12—C11—C20	123.9 (4)	C96—C97—C98	120.5 (4)
C12—C11—O2	119.7 (4)	C96—C97—H97	119.7
C20—C11—O2	116.1 (4)	C98—C97—H97	119.7
C11—C12—C13	117.0 (4)	C93—C98—C97	118.8 (4)
C11—C12—C2	121.8 (4)	C93—C98—C99	119.6 (4)
C13—C12—C2	121.2 (4)	C97—C98—C99	121.6 (4)
C14—C13—C18	118.1 (5)	C100—C99—C98	120.7 (4)
C14—C13—C12	122.2 (5)	C100—C99—H99	119.7
C18—C13—C12	119.7 (4)	C98—C99—H99	119.7
C15—C14—C13	121.4 (5)	C99—C100—C91	119.6 (4)
C15—C14—H14	119.3	C99—C100—H100	120.2
C13—C14—H14	119.3	C91—C100—H100	120.2
C14—C15—C16	119.5 (6)	C102—C101—O8	118.8 (4)
C14—C15—H15	120.3	C102—C101—C110	123.4 (4)
C16—C15—H15	120.3	O8—C101—C110	117.7 (4)
C17—C16—C15	120.6 (5)	C101—C102—C103	118.5 (4)
C17—C16—H16	119.7	C101—C102—C92	120.6 (4)
C15—C16—H16	119.7	C103—C102—C92	120.8 (4)
C16—C17—C18	120.6 (6)	C104—C103—C108	118.3 (4)
C16—C17—H17	119.7	C104—C103—C102	123.3 (4)
C18—C17—H17	119.7	C108—C103—C102	118.4 (4)
C17—C18—C13	119.6 (5)	C105—C104—C103	120.6 (4)
C17—C18—C19	121.5 (5)	C105—C104—H104	119.7
C13—C18—C19	118.9 (5)	C103—C104—H104	119.7
C20—C19—C18	120.8 (5)	C104—C105—C106	121.2 (5)
C20—C19—H19	119.6	C104—C105—H105	119.4
C18—C19—H19	119.6	C106—C105—H105	119.4
C19—C20—C11	119.0 (5)	C107—C106—C105	120.1 (4)
C19—C20—H20	120.5	C107—C106—H106	119.9
C11—C20—H20	120.5	C105—C106—H106	119.9
C22—C21—C30	123.8 (4)	C106—C107—C108	120.3 (5)
C22—C21—O3	117.9 (4)	C106—C107—H107	119.8
C30—C21—O3	118.2 (4)	C108—C107—H107	119.8
C21—C22—C23	117.7 (4)	C109—C108—C107	121.2 (4)
C21—C22—C32	120.4 (4)	C109—C108—C103	119.5 (4)
C23—C22—C32	121.9 (4)	C107—C108—C103	119.4 (4)
C24—C23—C28	118.5 (4)	C110—C109—C108	121.9 (4)
C24—C23—C22	123.0 (4)	C110—C109—H109	119.0
C28—C23—C22	118.4 (4)	C108—C109—H109	119.0
C25—C24—C23	121.5 (5)	C109—C110—C101	118.2 (4)
C25—C24—H24	119.3	C109—C110—H110	120.9
C23—C24—H24	119.3	C101—C110—H110	120.9
C24—C25—C26	120.3 (5)	C112—C111—C116	121.0 (4)
C24—C25—H25	119.9	C112—C111—N3	118.1 (4)
C26—C25—H25	119.9	C116—C111—N3	121.0 (4)
C27—C26—C25	120.0 (5)	C113—C112—C111	120.4 (5)
C27—C26—H26	120.0	C113—C112—H112	119.8
C25—C26—H26	120.0	C111—C112—H112	119.8
C26—C27—C28	120.6 (5)	C112—C113—C114	119.6 (4)
C26—C27—H27	119.7	C112—C113—H113	120.2
C28—C27—H27	119.7	C114—C113—H113	120.2
C27—C28—C29	121.4 (4)	C115—C114—C113	120.3 (5)
C27—C28—C23	119.2 (4)	C115—C114—H114	119.9
C29—C28—C23	119.5 (4)	C113—C114—H114	119.9
C30—C29—C28	121.5 (4)	C114—C115—C116	120.8 (5)
C30—C29—H29	119.2	C114—C115—H115	119.6
C28—C29—H29	119.2	C116—C115—H115	119.6
C29—C30—C21	118.3 (4)	C115—C116—C111	118.0 (4)
C29—C30—H30	120.8	C115—C116—C117	119.0 (4)
C21—C30—H30	120.8	C111—C116—C117	122.9 (4)
C32—C31—O4	119.3 (4)	C118—C117—C116	122.3 (4)
C32—C31—C40	123.3 (4)	C118—C117—Ir2	70.8 (2)
O4—C31—C40	117.3 (4)	C116—C117—Ir2	122.5 (3)
C31—C32—C33	117.8 (4)	C118—C117—H117	111.8
C31—C32—C22	120.3 (4)	C116—C117—H117	111.8
C33—C32—C22	121.7 (4)	Ir2—C117—H117	111.8
C34—C33—C38	118.6 (4)	C117—C118—C119	124.6 (4)
C34—C33—C32	122.3 (4)	C117—C118—Ir2	70.5 (2)
C38—C33—C32	119.0 (4)	C119—C118—Ir2	117.8 (3)
C35—C34—C33	119.8 (4)	C117—C118—H118	112.5
C35—C34—H34	120.1	C119—C118—H118	112.5
C33—C34—H34	120.1	Ir2—C118—H118	112.5
C34—C35—C36	122.0 (5)	C124—C119—C120	117.1 (4)
C34—C35—H35	119.0	C124—C119—C118	124.3 (4)
C36—C35—H35	119.0	C120—C119—C118	118.6 (4)
C37—C36—C35	119.7 (5)	C121—C120—C119	121.5 (5)
C37—C36—H36	120.2	C121—C120—H120	119.2
C35—C36—H36	120.2	C119—C120—H120	119.2
C36—C37—C38	121.3 (4)	C120—C121—C122	120.3 (4)
C36—C37—H37	119.4	C120—C121—H121	119.9
C38—C37—H37	119.4	C122—C121—H121	119.9
C39—C38—C37	121.9 (4)	C121—C122—C123	120.2 (5)
C39—C38—C33	119.5 (4)	C121—C122—H122	119.9
C37—C38—C33	118.6 (4)	C123—C122—H122	119.9
C40—C39—C38	121.3 (4)	C124—C123—C122	118.5 (5)
C40—C39—H39	119.3	C124—C123—H123	120.7
C38—C39—H39	119.3	C122—C123—H123	120.7
C39—C40—C31	118.5 (4)	C119—C124—C123	122.4 (4)
C39—C40—H40	120.8	C119—C124—N3	120.4 (4)
C31—C40—H40	120.8	C123—C124—N3	117.2 (4)
C42—C41—C46	121.2 (5)	C126—C125—C130	122.5 (4)
C42—C41—N1	118.5 (5)	C126—C125—N4	117.4 (4)
C46—C41—N1	120.3 (4)	C130—C125—N4	120.1 (4)
C43—C42—C41	119.8 (5)	C125—C126—C127	119.2 (5)
C43—C42—H42	120.1	C125—C126—H126	120.4
C41—C42—H42	120.1	C127—C126—H126	120.4
C42—C43—C44	120.2 (6)	C128—C127—C126	120.0 (5)
C42—C43—H43	119.9	C128—C127—H127	120.0
C44—C43—H43	119.9	C126—C127—H127	120.0
C45—C44—C43	119.6 (5)	C127—C128—C129	120.4 (5)
C45—C44—H44	120.2	C127—C128—H128	119.8
C43—C44—H44	120.2	C129—C128—H128	119.8
C44—C45—C46	122.6 (5)	C130—C129—C128	120.5 (5)
C44—C45—H45	118.7	C130—C129—H129	119.8
C46—C45—H45	118.7	C128—C129—H129	119.8
C45—C46—C41	116.5 (4)	C125—C130—C129	117.4 (4)
C45—C46—C47	119.6 (4)	C125—C130—C131	124.4 (4)
C41—C46—C47	124.0 (4)	C129—C130—C131	118.2 (4)
C48—C47—C46	125.3 (4)	C132—C131—C130	123.7 (4)
C48—C47—Ir1	70.8 (2)	C132—C131—Ir2	70.7 (2)
C46—C47—Ir1	117.7 (3)	C130—C131—Ir2	119.6 (3)
C48—C47—H47	112.2	C132—C131—H131	112.3
C46—C47—H47	112.2	C130—C131—H131	112.3
Ir1—C47—H47	112.2	Ir2—C131—H131	112.3
C47—C48—C49	124.1 (4)	C131—C132—C133	123.4 (4)
C47—C48—Ir1	70.4 (2)	C131—C132—Ir2	70.6 (2)
C49—C48—Ir1	122.0 (3)	C133—C132—Ir2	120.9 (3)
C47—C48—H48	111.5	C131—C132—H132	112.0
C49—C48—H48	111.5	C133—C132—H132	112.0
Ir1—C48—H48	111.5	Ir2—C132—H132	112.0
C50—C49—C54	117.1 (4)	C134—C133—C138	117.2 (4)
C50—C49—C48	119.3 (4)	C134—C133—C132	119.1 (4)
C54—C49—C48	123.4 (4)	C138—C133—C132	123.6 (4)
C51—C50—C49	120.5 (5)	C135—C134—C133	121.6 (5)
C51—C50—H50	119.7	C135—C134—H134	119.2
C49—C50—H50	119.7	C133—C134—H134	119.2
C52—C51—C50	121.0 (5)	C136—C135—C134	119.8 (4)
C52—C51—H51	119.5	C136—C135—H135	120.1
C50—C51—H51	119.5	C134—C135—H135	120.1
C51—C52—C53	119.4 (5)	C135—C136—C137	120.0 (4)
C51—C52—H52	120.3	C135—C136—H136	120.0
C53—C52—H52	120.3	C137—C136—H136	120.0
C54—C53—C52	120.1 (5)	C138—C137—C136	119.9 (4)
C54—C53—H53	119.9	C138—C137—H137	120.1
C52—C53—H53	119.9	C136—C137—H137	120.1
C53—C54—C49	121.7 (4)	C137—C138—C133	121.5 (4)
C53—C54—N1	118.6 (4)	C137—C138—N4	118.1 (4)
C49—C54—N1	119.7 (4)	C133—C138—N4	120.4 (4)
C56—C55—C60	121.6 (4)	C142—C141—C146	118.4 (7)
C56—C55—N2	119.0 (4)	C142—C141—H141	120.8
C60—C55—N2	119.4 (4)	C146—C141—H141	120.8
C57—C56—C55	119.7 (5)	C141—C142—C143	120.9 (7)
C57—C56—H56	120.1	C141—C142—H142	119.5
C55—C56—H56	120.1	C143—C142—H142	119.5
C56—C57—C58	119.8 (5)	C142—C143—C144	121.8 (7)
C56—C57—H57	120.1	C142—C143—H143	119.1
C58—C57—H57	120.1	C144—C143—H143	119.1
C57—C58—C59	120.1 (5)	C145—C144—C143	117.2 (7)
C57—C58—H58	119.9	C145—C144—H144	121.4
C59—C58—H58	119.9	C143—C144—H144	121.4
C58—C59—C60	121.1 (5)	C144—C145—C146	122.1 (7)
C58—C59—H59	119.5	C144—C145—H145	118.9
C60—C59—H59	119.5	C146—C145—H145	118.9
C55—C60—C59	117.6 (4)	C141—C146—C145	119.5 (7)
C55—C60—C61	123.7 (4)	C141—C146—H146	120.2
C59—C60—C61	118.8 (4)	C145—C146—H146	120.2
C62—C61—C60	123.4 (4)	C152—C151—C156	117.6 (7)
C62—C61—Ir1	70.5 (2)	C152—C151—H151	121.2
C60—C61—Ir1	122.2 (3)	C156—C151—H151	121.2
C62—C61—H61	111.6	C151—C152—C153	121.3 (7)
C60—C61—H61	111.6	C151—C152—H152	119.4
Ir1—C61—H61	111.6	C153—C152—H152	119.4
C61—C62—C63	125.6 (4)	C152—C153—C154	122.4 (7)
C61—C62—Ir1	70.8 (2)	C152—C153—H153	118.8
C63—C62—Ir1	117.8 (3)	C154—C153—H153	118.8
C61—C62—H62	112.1	C155—C154—C153	116.0 (7)
C63—C62—H62	112.1	C155—C154—H154	122.0
Ir1—C62—H62	112.1	C153—C154—H154	122.0
C68—C63—C64	117.2 (4)	C154—C155—C156	122.5 (7)
C68—C63—C62	123.6 (4)	C154—C155—H155	118.7
C64—C63—C62	119.1 (4)	C156—C155—H155	118.7
C65—C64—C63	120.5 (5)	C155—C156—C151	120.0 (7)
C65—C64—H64	119.7	C155—C156—H156	120.0
C63—C64—H64	119.7	C151—C156—H156	120.0
C66—C65—C64	121.2 (5)	C162—C161—H158	109.5
C66—C65—H65	119.4	C162—C161—H159	109.5
C64—C65—H65	119.4	H158—C161—H159	109.5
C65—C66—C67	119.5 (5)	C162—C161—H160	109.5
C65—C66—H66	120.3	H158—C161—H160	109.5
C67—C66—H66	120.3	H159—C161—H160	109.5
C66—C67—C68	119.8 (5)	C163—C162—C161	111.4 (7)
C66—C67—H67	120.1	C163—C162—H161	109.4
C68—C67—H67	120.1	C161—C162—H161	109.4
C67—C68—C63	121.6 (4)	C163—C162—H162	109.4
C67—C68—N2	118.2 (4)	C161—C162—H162	109.4
C63—C68—N2	120.1 (4)	H161—C162—H162	108.0
P3—Ir2—P4	179.35 (4)	C162—C163—C164	111.3 (7)
P3—Ir2—Cl2	89.45 (4)	C162—C163—H163	109.4
P4—Ir2—Cl2	89.91 (4)	C164—C163—H163	109.4
C117—Ir2—P3	86.33 (12)	C162—C163—H164	109.4
C118—Ir2—P3	89.74 (12)	C164—C163—H164	109.4
C131—Ir2—P3	91.57 (12)	H163—C163—H164	108.0
C132—Ir2—P3	92.96 (12)	C163—C164—C165	116.7 (9)
C117—Ir2—P4	94.16 (12)	C163—C164—H165	108.1
C118—Ir2—P4	90.38 (12)	C165—C164—H165	108.1
C131—Ir2—P4	88.37 (12)	C163—C164—H166	108.1
C132—Ir2—P4	87.40 (12)	C165—C164—H166	108.1
C117—Ir2—Cl2	130.44 (12)	H165—C164—H166	107.3
C118—Ir2—Cl2	91.96 (12)	C164—C165—H167	109.5
C131—Ir2—Cl2	93.36 (12)	C164—C165—H168	109.5
C132—Ir2—Cl2	132.04 (13)	H167—C165—H168	109.5
C117—Ir2—C118	38.74 (16)	C164—C165—H169	109.5
C117—Ir2—C131	136.06 (16)	H167—C165—H169	109.5
C117—Ir2—C132	97.51 (17)	H168—C165—H169	109.5
C118—Ir2—C131	174.52 (17)	C172—C171—H171	109.5
C118—Ir2—C132	135.90 (17)	C172—C171—H172	109.5
C131—Ir2—C132	38.71 (17)	H171—C171—H172	109.5
O6—P3—O5	103.46 (15)	C172—C171—H173	109.5
O6—P3—N3	99.62 (18)	H171—C171—H173	109.5
O5—P3—N3	103.96 (17)	H172—C171—H173	109.5
O6—P3—Ir2	123.01 (12)	C173—C172—C171	111.3 (7)
O5—P3—Ir2	113.23 (12)	C173—C172—H174	109.4
N3—P3—Ir2	111.27 (13)	C171—C172—H174	109.4
O8—P4—O7	103.71 (15)	C173—C172—H175	109.4
O8—P4—N4	98.59 (16)	C171—C172—H175	109.4
O7—P4—N4	104.51 (17)	H174—C172—H175	108.0
O8—P4—Ir2	119.65 (12)	C172—C173—C174	110.4 (7)
O7—P4—Ir2	115.80 (11)	C172—C173—H176	109.6
N4—P4—Ir2	112.27 (12)	C174—C173—H176	109.6
C71—O5—P3	122.7 (2)	C172—C173—H177	109.6
C81—O6—P3	116.0 (3)	C174—C173—H177	109.6
C91—O7—P4	119.5 (2)	H176—C173—H177	108.1
C101—O8—P4	120.6 (3)	C175—C174—C173	116.8 (9)
C111—N3—C124	111.3 (3)	C175—C174—H178	108.1
C111—N3—P3	111.0 (3)	C173—C174—H178	108.1
C124—N3—P3	114.3 (3)	C175—C174—H179	108.1
C138—N4—C125	111.2 (3)	C173—C174—H179	108.1
C138—N4—P4	112.7 (3)	H178—C174—H179	107.3
C125—N4—P4	112.7 (3)	C174—C175—H180	109.5
C72—C71—O5	120.3 (4)	C174—C175—H181	109.5
C72—C71—C80	122.9 (4)	H180—C175—H181	109.5
O5—C71—C80	116.6 (4)	C174—C175—H182	109.5
C71—C72—C73	118.1 (4)	H180—C175—H182	109.5
C71—C72—C82	120.6 (4)	H181—C175—H182	109.5
C47—Ir1—P1—O2	132.51 (16)	C118—Ir2—P3—O5	127.50 (17)
C62—Ir1—P1—O2	−45.49 (17)	Cl2—Ir2—P3—O5	−140.53 (13)
C48—Ir1—P1—O2	93.72 (17)	C131—Ir2—P3—N3	−163.84 (18)
C61—Ir1—P1—O2	−6.84 (17)	C132—Ir2—P3—N3	−125.12 (18)
Cl1—Ir1—P1—O2	−136.08 (12)	C117—Ir2—P3—N3	−27.78 (18)
C47—Ir1—P1—O1	−102.38 (19)	C118—Ir2—P3—N3	10.84 (18)
C62—Ir1—P1—O1	79.6 (2)	Cl2—Ir2—P3—N3	102.81 (14)
C48—Ir1—P1—O1	−141.2 (2)	C131—Ir2—P4—O8	−97.57 (18)
C61—Ir1—P1—O1	118.27 (19)	C132—Ir2—P4—O8	−136.30 (18)
Cl1—Ir1—P1—O1	−10.97 (16)	C117—Ir2—P4—O8	126.35 (17)
C47—Ir1—P1—N1	14.75 (18)	C118—Ir2—P4—O8	87.76 (17)
C62—Ir1—P1—N1	−163.26 (19)	Cl2—Ir2—P4—O8	−4.21 (14)
C48—Ir1—P1—N1	−24.04 (19)	C131—Ir2—P4—O7	137.10 (17)
C61—Ir1—P1—N1	−124.61 (19)	C132—Ir2—P4—O7	98.37 (17)
Cl1—Ir1—P1—N1	106.15 (15)	C117—Ir2—P4—O7	1.03 (17)
C47—Ir1—P2—O3	79.37 (18)	C118—Ir2—P4—O7	−37.57 (17)
C62—Ir1—P2—O3	−102.64 (18)	Cl2—Ir2—P4—O7	−129.53 (13)
C48—Ir1—P2—O3	118.16 (18)	C131—Ir2—P4—N4	17.19 (18)
C61—Ir1—P2—O3	−141.30 (18)	C132—Ir2—P4—N4	−21.54 (18)
Cl1—Ir1—P2—O3	−12.23 (14)	C117—Ir2—P4—N4	−118.89 (18)
C47—Ir1—P2—O4	−45.46 (17)	C118—Ir2—P4—N4	−157.48 (17)
C62—Ir1—P2—O4	132.53 (17)	Cl2—Ir2—P4—N4	110.55 (14)
C48—Ir1—P2—O4	−6.67 (17)	O6—P3—O5—C71	28.0 (3)
C61—Ir1—P2—O4	93.87 (17)	N3—P3—O5—C71	−75.7 (3)
Cl1—Ir1—P2—O4	−137.06 (13)	Ir2—P3—O5—C71	163.4 (3)
C47—Ir1—P2—N2	−163.38 (18)	O5—P3—O6—C81	59.3 (3)
C62—Ir1—P2—N2	14.61 (18)	N3—P3—O6—C81	166.2 (3)
C48—Ir1—P2—N2	−124.60 (18)	Ir2—P3—O6—C81	−70.5 (3)
C61—Ir1—P2—N2	−24.06 (18)	O8—P4—O7—C91	47.3 (3)
Cl1—Ir1—P2—N2	105.02 (14)	N4—P4—O7—C91	−55.5 (3)
O2—P1—O1—C1	51.7 (3)	Ir2—P4—O7—C91	−179.6 (2)
N1—P1—O1—C1	159.7 (3)	O7—P4—O8—C101	41.2 (3)
Ir1—P1—O1—C1	−76.2 (3)	N4—P4—O8—C101	148.6 (3)
O1—P1—O2—C11	35.7 (4)	Ir2—P4—O8—C101	−89.6 (3)
N1—P1—O2—C11	−66.7 (3)	O6—P3—N3—C111	−159.0 (3)
Ir1—P1—O2—C11	171.0 (3)	O5—P3—N3—C111	−52.4 (3)
O4—P2—O3—C21	53.6 (3)	Ir2—P3—N3—C111	69.8 (3)
N2—P2—O3—C21	160.3 (3)	O6—P3—N3—C124	74.1 (3)
Ir1—P2—O3—C21	−75.6 (3)	O5—P3—N3—C124	−179.3 (3)
O3—P2—O4—C31	36.8 (3)	Ir2—P3—N3—C124	−57.1 (3)
N2—P2—O4—C31	−66.1 (3)	O8—P4—N4—C138	−168.0 (3)
Ir1—P2—O4—C31	170.8 (3)	O7—P4—N4—C138	−61.4 (3)
O2—P1—N1—C41	178.1 (3)	Ir2—P4—N4—C138	64.9 (3)
O1—P1—N1—C41	70.8 (3)	O8—P4—N4—C125	65.1 (3)
Ir1—P1—N1—C41	−60.8 (3)	O7—P4—N4—C125	171.7 (3)
O2—P1—N1—C54	−54.6 (3)	Ir2—P4—N4—C125	−62.0 (3)
O1—P1—N1—C54	−161.9 (3)	P3—O5—C71—C72	−66.8 (5)
Ir1—P1—N1—C54	66.5 (3)	P3—O5—C71—C80	118.8 (4)
O3—P2—N2—C55	−162.7 (3)	O5—C71—C72—C73	−179.1 (3)
O4—P2—N2—C55	−56.2 (3)	C80—C71—C72—C73	−5.0 (6)
Ir1—P2—N2—C55	67.2 (3)	O5—C71—C72—C82	3.9 (6)
O3—P2—N2—C68	69.6 (3)	C80—C71—C72—C82	177.9 (4)
O4—P2—N2—C68	176.2 (3)	C71—C72—C73—C74	−172.9 (4)
Ir1—P2—N2—C68	−60.4 (3)	C82—C72—C73—C74	4.2 (7)
P1—O1—C1—C2	−73.2 (5)	C71—C72—C73—C78	5.9 (6)
P1—O1—C1—C10	110.9 (4)	C82—C72—C73—C78	−177.1 (4)
C10—C1—C2—C3	−7.8 (7)	C78—C73—C74—C75	2.9 (7)
O1—C1—C2—C3	176.6 (4)	C72—C73—C74—C75	−178.3 (4)
C10—C1—C2—C12	173.5 (5)	C73—C74—C75—C76	−0.5 (8)
O1—C1—C2—C12	−2.2 (7)	C74—C75—C76—C77	−2.2 (8)
C1—C2—C3—C8	7.6 (7)	C75—C76—C77—C78	2.2 (8)
C12—C2—C3—C8	−173.6 (4)	C76—C77—C78—C79	−178.4 (5)
C1—C2—C3—C4	−170.5 (4)	C76—C77—C78—C73	0.4 (8)
C12—C2—C3—C4	8.2 (7)	C74—C73—C78—C77	−2.9 (6)
C8—C3—C4—C5	3.9 (7)	C72—C73—C78—C77	178.3 (4)
C2—C3—C4—C5	−177.9 (5)	C74—C73—C78—C79	175.9 (4)
C3—C4—C5—C6	−0.2 (8)	C72—C73—C78—C79	−2.9 (6)
C4—C5—C6—C7	−2.8 (9)	C77—C78—C79—C80	177.6 (5)
C5—C6—C7—C8	1.9 (9)	C73—C78—C79—C80	−1.1 (7)
C6—C7—C8—C3	1.8 (8)	C78—C79—C80—C71	2.1 (7)
C6—C7—C8—C9	−178.3 (5)	C72—C71—C80—C79	1.0 (7)
C4—C3—C8—C7	−4.7 (7)	O5—C71—C80—C79	175.3 (4)
C2—C3—C8—C7	177.1 (5)	P3—O6—C81—C82	−71.1 (4)
C4—C3—C8—C9	175.5 (5)	P3—O6—C81—C90	110.4 (4)
C2—C3—C8—C9	−2.8 (7)	C90—C81—C82—C83	−10.5 (7)
C7—C8—C9—C10	177.7 (5)	O6—C81—C82—C83	171.0 (4)
C3—C8—C9—C10	−2.5 (8)	C90—C81—C82—C72	167.6 (4)
C8—C9—C10—C1	2.7 (8)	O6—C81—C82—C72	−10.9 (6)
C2—C1—C10—C9	2.6 (8)	C71—C72—C82—C81	53.8 (6)
O1—C1—C10—C9	178.3 (4)	C73—C72—C82—C81	−123.2 (5)
P1—O2—C11—C12	−63.8 (5)	C71—C72—C82—C83	−128.1 (5)
P1—O2—C11—C20	122.0 (4)	C73—C72—C82—C83	54.9 (6)
C20—C11—C12—C13	−9.0 (8)	C81—C82—C83—C84	−169.8 (4)
O2—C11—C12—C13	177.3 (4)	C72—C82—C83—C84	12.0 (7)
C20—C11—C12—C2	169.5 (5)	C81—C82—C83—C88	7.5 (6)
O2—C11—C12—C2	−4.3 (7)	C72—C82—C83—C88	−170.7 (4)
C1—C2—C12—C11	52.9 (7)	C82—C83—C84—C85	177.3 (5)
C3—C2—C12—C11	−125.9 (5)	C88—C83—C84—C85	−0.1 (7)
C1—C2—C12—C13	−128.7 (5)	C83—C84—C85—C86	0.2 (8)
C3—C2—C12—C13	52.5 (7)	C84—C85—C86—C87	−0.5 (9)
C11—C12—C13—C14	−169.7 (5)	C85—C86—C87—C88	0.6 (9)
C2—C12—C13—C14	11.8 (8)	C86—C87—C88—C89	−177.9 (5)
C11—C12—C13—C18	8.9 (8)	C86—C87—C88—C83	−0.5 (8)
C2—C12—C13—C18	−169.6 (5)	C84—C83—C88—C87	0.2 (7)
C18—C13—C14—C15	2.9 (9)	C82—C83—C88—C87	−177.2 (4)
C12—C13—C14—C15	−178.4 (6)	C84—C83—C88—C89	177.7 (4)
C13—C14—C15—C16	0.3 (10)	C82—C83—C88—C89	0.2 (7)
C14—C15—C16—C17	−2.8 (11)	C87—C88—C89—C90	171.8 (5)
C15—C16—C17—C18	1.9 (11)	C83—C88—C89—C90	−5.6 (8)
C16—C17—C18—C13	1.4 (10)	C88—C89—C90—C81	3.0 (8)
C16—C17—C18—C19	−177.5 (7)	C82—C81—C90—C89	5.4 (7)
C14—C13—C18—C17	−3.8 (9)	O6—C81—C90—C89	−176.1 (4)
C12—C13—C18—C17	177.6 (6)	P4—O7—C91—C92	−66.7 (5)
C14—C13—C18—C19	175.2 (5)	P4—O7—C91—C100	117.7 (4)
C12—C13—C18—C19	−3.5 (8)	C100—C91—C92—C93	−11.2 (6)
C17—C18—C19—C20	176.5 (6)	O7—C91—C92—C93	173.5 (4)
C13—C18—C19—C20	−2.5 (9)	C100—C91—C92—C102	166.7 (4)
C18—C19—C20—C11	2.8 (9)	O7—C91—C92—C102	−8.6 (6)
C12—C11—C20—C19	3.3 (8)	C91—C92—C93—C98	10.2 (6)
O2—C11—C20—C19	177.2 (5)	C102—C92—C93—C98	−167.8 (4)
P2—O3—C21—C22	−73.7 (4)	C91—C92—C93—C94	−168.2 (4)
P2—O3—C21—C30	109.6 (4)	C102—C92—C93—C94	13.9 (6)
C30—C21—C22—C23	−9.8 (6)	C98—C93—C94—C95	1.5 (7)
O3—C21—C22—C23	173.7 (4)	C92—C93—C94—C95	179.9 (4)
C30—C21—C22—C32	170.6 (4)	C93—C94—C95—C96	1.2 (7)
O3—C21—C22—C32	−5.8 (6)	C94—C95—C96—C97	−2.1 (8)
C21—C22—C23—C24	−170.7 (4)	C95—C96—C97—C98	0.3 (7)
C32—C22—C23—C24	8.8 (7)	C94—C93—C98—C97	−3.3 (6)
C21—C22—C23—C28	7.4 (6)	C92—C93—C98—C97	178.3 (4)
C32—C22—C23—C28	−173.0 (4)	C94—C93—C98—C99	175.2 (4)
C28—C23—C24—C25	2.8 (7)	C92—C93—C98—C99	−3.2 (6)
C22—C23—C24—C25	−179.1 (4)	C96—C97—C98—C93	2.4 (7)
C23—C24—C25—C26	−0.9 (7)	C96—C97—C98—C99	−176.1 (5)
C24—C25—C26—C27	−1.2 (7)	C93—C98—C99—C100	−3.5 (7)
C25—C26—C27—C28	1.5 (7)	C97—C98—C99—C100	175.0 (4)
C26—C27—C28—C29	−179.7 (5)	C98—C99—C100—C91	2.9 (7)
C26—C27—C28—C23	0.4 (7)	C92—C91—C100—C99	4.8 (7)
C24—C23—C28—C27	−2.5 (6)	O7—C91—C100—C99	−179.7 (4)
C22—C23—C28—C27	179.3 (4)	P4—O8—C101—C102	−74.3 (4)
C24—C23—C28—C29	177.6 (4)	P4—O8—C101—C110	109.7 (4)
C22—C23—C28—C29	−0.6 (6)	O8—C101—C102—C103	−178.9 (3)
C27—C28—C29—C30	175.5 (4)	C110—C101—C102—C103	−3.2 (6)
C23—C28—C29—C30	−4.6 (7)	O8—C101—C102—C92	4.2 (6)
C28—C29—C30—C21	2.7 (7)	C110—C101—C102—C92	180.0 (4)
C22—C21—C30—C29	4.7 (7)	C91—C92—C102—C101	51.9 (6)
O3—C21—C30—C29	−178.8 (4)	C93—C92—C102—C101	−130.3 (4)
P2—O4—C31—C32	−69.6 (5)	C91—C92—C102—C103	−124.9 (5)
P2—O4—C31—C40	113.6 (4)	C93—C92—C102—C103	53.0 (6)
O4—C31—C32—C33	175.0 (4)	C101—C102—C103—C104	−173.9 (4)
C40—C31—C32—C33	−8.4 (6)	C92—C102—C103—C104	2.9 (6)
O4—C31—C32—C22	−0.1 (6)	C101—C102—C103—C108	3.3 (6)
C40—C31—C32—C22	176.6 (4)	C92—C102—C103—C108	−179.8 (4)
C21—C22—C32—C31	54.8 (6)	C108—C103—C104—C105	3.4 (7)
C23—C22—C32—C31	−124.7 (4)	C102—C103—C104—C105	−179.3 (4)
C21—C22—C32—C33	−120.0 (4)	C103—C104—C105—C106	−1.1 (7)
C23—C22—C32—C33	60.5 (6)	C104—C105—C106—C107	−1.2 (8)
C31—C32—C33—C34	−173.1 (4)	C105—C106—C107—C108	1.1 (8)
C22—C32—C33—C34	1.9 (6)	C106—C107—C108—C109	−178.4 (5)
C31—C32—C33—C38	2.9 (6)	C106—C107—C108—C103	1.3 (7)
C22—C32—C33—C38	177.8 (4)	C104—C103—C108—C109	176.2 (4)
C38—C33—C34—C35	−1.7 (6)	C102—C103—C108—C109	−1.2 (6)
C32—C33—C34—C35	174.3 (4)	C104—C103—C108—C107	−3.5 (6)
C33—C34—C35—C36	1.2 (7)	C102—C103—C108—C107	179.1 (4)
C34—C35—C36—C37	0.6 (7)	C107—C108—C109—C110	178.3 (4)
C35—C36—C37—C38	−1.9 (7)	C103—C108—C109—C110	−1.4 (7)
C36—C37—C38—C39	−178.0 (4)	C108—C109—C110—C101	1.7 (7)
C36—C37—C38—C33	1.3 (7)	C102—C101—C110—C109	0.6 (7)
C34—C33—C38—C39	179.8 (4)	O8—C101—C110—C109	176.4 (4)
C32—C33—C38—C39	3.7 (6)	C124—N3—C111—C112	−108.1 (4)
C34—C33—C38—C37	0.5 (6)	P3—N3—C111—C112	123.4 (4)
C32—C33—C38—C37	−175.7 (4)	C124—N3—C111—C116	72.1 (5)
C37—C38—C39—C40	174.1 (4)	P3—N3—C111—C116	−56.5 (4)
C33—C38—C39—C40	−5.2 (7)	C116—C111—C112—C113	0.9 (7)
C38—C39—C40—C31	0.0 (7)	N3—C111—C112—C113	−178.9 (4)
C32—C31—C40—C39	7.1 (7)	C111—C112—C113—C114	0.5 (7)
O4—C31—C40—C39	−176.2 (4)	C112—C113—C114—C115	−0.7 (7)
C54—N1—C41—C42	114.0 (5)	C113—C114—C115—C116	−0.5 (7)
P1—N1—C41—C42	−118.7 (4)	C114—C115—C116—C111	1.9 (7)
C54—N1—C41—C46	−67.5 (5)	C114—C115—C116—C117	−174.9 (4)
P1—N1—C41—C46	59.8 (5)	C112—C111—C116—C115	−2.1 (6)
C46—C41—C42—C43	1.0 (7)	N3—C111—C116—C115	177.7 (4)
N1—C41—C42—C43	179.5 (4)	C112—C111—C116—C117	174.6 (4)
C41—C42—C43—C44	−2.3 (8)	N3—C111—C116—C117	−5.5 (6)
C42—C43—C44—C45	1.1 (8)	C115—C116—C117—C118	137.7 (4)
C43—C44—C45—C46	1.5 (8)	C111—C116—C117—C118	−39.0 (6)
C44—C45—C46—C41	−2.6 (7)	C115—C116—C117—Ir2	−135.7 (4)
C44—C45—C46—C47	178.6 (4)	C111—C116—C117—Ir2	47.6 (6)
C42—C41—C46—C45	1.4 (6)	C131—Ir2—C117—C118	−177.4 (3)
N1—C41—C46—C45	−177.1 (4)	C132—Ir2—C117—C118	−173.3 (3)
C42—C41—C46—C47	−179.9 (4)	P4—Ir2—C117—C118	−85.4 (2)
N1—C41—C46—C47	1.7 (6)	P3—Ir2—C117—C118	94.2 (2)
C45—C46—C47—C48	−149.4 (4)	Cl2—Ir2—C117—C118	8.0 (3)
C41—C46—C47—C48	31.9 (6)	C131—Ir2—C117—C116	66.0 (4)
C45—C46—C47—Ir1	125.4 (4)	C132—Ir2—C117—C116	70.0 (4)
C41—C46—C47—Ir1	−53.3 (5)	C118—Ir2—C117—C116	−116.7 (5)
C61—Ir1—C47—C48	3.0 (4)	P4—Ir2—C117—C116	157.9 (3)
P2—Ir1—C47—C48	89.1 (2)	P3—Ir2—C117—C116	−22.5 (3)
P1—Ir1—C47—C48	−86.0 (2)	Cl2—Ir2—C117—C116	−108.6 (3)
Cl1—Ir1—C47—C48	−177.8 (2)	C116—C117—C118—C119	6.1 (7)
C48—Ir1—C47—C46	120.6 (5)	Ir2—C117—C118—C119	−110.9 (4)
C61—Ir1—C47—C46	123.6 (3)	C116—C117—C118—Ir2	117.0 (4)
P2—Ir1—C47—C46	−150.3 (3)	C132—Ir2—C118—C117	9.5 (4)
P1—Ir1—C47—C46	34.6 (3)	P4—Ir2—C118—C117	96.2 (2)
Cl1—Ir1—C47—C46	−57.2 (3)	P3—Ir2—C118—C117	−84.5 (2)
C46—C47—C48—C49	5.1 (7)	Cl2—Ir2—C118—C117	−173.9 (2)
Ir1—C47—C48—C49	116.0 (4)	C132—Ir2—C118—C119	129.1 (3)
C46—C47—C48—Ir1	−110.9 (4)	C117—Ir2—C118—C119	119.6 (4)
C62—Ir1—C48—C47	179.8 (3)	P4—Ir2—C118—C119	−144.2 (3)
C61—Ir1—C48—C47	−178.0 (3)	P3—Ir2—C118—C119	35.1 (3)
P2—Ir1—C48—C47	−92.2 (2)	Cl2—Ir2—C118—C119	−54.3 (3)
P1—Ir1—C48—C47	91.8 (2)	C117—C118—C119—C124	35.8 (7)
Cl1—Ir1—C48—C47	2.9 (3)	Ir2—C118—C119—C124	−48.7 (5)
C47—Ir1—C48—C49	−118.7 (5)	C117—C118—C119—C120	−143.7 (4)
C62—Ir1—C48—C49	61.1 (5)	Ir2—C118—C119—C120	131.8 (4)
C61—Ir1—C48—C49	63.3 (4)	C124—C119—C120—C121	1.0 (7)
P2—Ir1—C48—C49	149.1 (3)	C118—C119—C120—C121	−179.5 (4)
P1—Ir1—C48—C49	−26.9 (3)	C119—C120—C121—C122	−0.3 (8)
Cl1—Ir1—C48—C49	−115.8 (3)	C120—C121—C122—C123	0.3 (8)
C47—C48—C49—C50	138.9 (5)	C121—C122—C123—C124	−1.1 (8)
Ir1—C48—C49—C50	−134.1 (4)	C120—C119—C124—C123	−1.8 (7)
C47—C48—C49—C54	−34.8 (6)	C118—C119—C124—C123	178.7 (4)
Ir1—C48—C49—C54	52.2 (6)	C120—C119—C124—N3	176.4 (4)
C54—C49—C50—C51	2.9 (7)	C118—C119—C124—N3	−3.0 (7)
C48—C49—C50—C51	−171.3 (5)	C122—C123—C124—C119	1.9 (7)
C49—C50—C51—C52	−0.3 (8)	C122—C123—C124—N3	−176.4 (4)
C50—C51—C52—C53	−2.0 (9)	C111—N3—C124—C119	−64.8 (5)
C51—C52—C53—C54	1.7 (9)	P3—N3—C124—C119	62.0 (5)
C52—C53—C54—C49	0.9 (8)	C111—N3—C124—C123	113.5 (5)
C52—C53—C54—N1	179.8 (5)	P3—N3—C124—C123	−119.7 (4)
C50—C49—C54—C53	−3.1 (7)	C138—N4—C125—C126	111.8 (4)
C48—C49—C54—C53	170.7 (5)	P4—N4—C125—C126	−120.5 (4)
C50—C49—C54—N1	177.9 (4)	C138—N4—C125—C130	−67.7 (5)
C48—C49—C54—N1	−8.2 (7)	P4—N4—C125—C130	59.9 (5)
C41—N1—C54—C53	−105.9 (5)	C130—C125—C126—C127	0.4 (7)
P1—N1—C54—C53	127.1 (4)	N4—C125—C126—C127	−179.1 (4)
C41—N1—C54—C49	73.1 (5)	C125—C126—C127—C128	0.4 (8)
P1—N1—C54—C49	−53.9 (5)	C126—C127—C128—C129	−1.5 (9)
C68—N2—C55—C56	−107.5 (5)	C127—C128—C129—C130	1.8 (9)
P2—N2—C55—C56	124.5 (4)	C126—C125—C130—C129	−0.1 (7)
C68—N2—C55—C60	72.9 (5)	N4—C125—C130—C129	179.4 (4)
P2—N2—C55—C60	−55.0 (5)	C126—C125—C130—C131	−179.6 (4)
C60—C55—C56—C57	1.8 (7)	N4—C125—C130—C131	−0.2 (7)
N2—C55—C56—C57	−177.7 (4)	C128—C129—C130—C125	−1.0 (7)
C55—C56—C57—C58	0.9 (8)	C128—C129—C130—C131	178.6 (5)
C56—C57—C58—C59	−1.6 (8)	C125—C130—C131—C132	37.0 (7)
C57—C58—C59—C60	−0.2 (8)	C129—C130—C131—C132	−142.5 (5)
C56—C55—C60—C59	−3.5 (7)	C125—C130—C131—Ir2	−48.5 (6)
N2—C55—C60—C59	176.0 (4)	C129—C130—C131—Ir2	132.0 (4)
C56—C55—C60—C61	174.0 (4)	C117—Ir2—C131—C132	6.4 (4)
N2—C55—C60—C61	−6.4 (7)	P4—Ir2—C131—C132	−87.9 (2)
C58—C59—C60—C55	2.7 (7)	P3—Ir2—C131—C132	92.8 (2)
C58—C59—C60—C61	−175.0 (5)	Cl2—Ir2—C131—C132	−177.7 (2)
C55—C60—C61—C62	−36.2 (7)	C132—Ir2—C131—C130	118.5 (5)
C59—C60—C61—C62	141.4 (5)	C117—Ir2—C131—C130	124.9 (3)
C55—C60—C61—Ir1	50.6 (6)	P4—Ir2—C131—C130	30.6 (3)
C59—C60—C61—Ir1	−131.9 (4)	P3—Ir2—C131—C130	−148.8 (3)
C47—Ir1—C61—C62	−179.6 (3)	Cl2—Ir2—C131—C130	−59.2 (3)
C48—Ir1—C61—C62	−177.7 (3)	C130—C131—C132—C133	1.6 (6)
P2—Ir1—C61—C62	91.8 (2)	Ir2—C131—C132—C133	114.9 (4)
P1—Ir1—C61—C62	−91.8 (2)	C130—C131—C132—Ir2	−113.3 (4)
Cl1—Ir1—C61—C62	1.4 (3)	C117—Ir2—C132—C131	−175.5 (3)
C47—Ir1—C61—C60	62.5 (5)	C118—Ir2—C132—C131	178.5 (3)
C62—Ir1—C61—C60	−117.9 (5)	P4—Ir2—C132—C131	90.6 (2)
C48—Ir1—C61—C60	64.4 (4)	P3—Ir2—C132—C131	−88.8 (2)
P2—Ir1—C61—C60	−26.1 (3)	Cl2—Ir2—C132—C131	3.1 (3)
P1—Ir1—C61—C60	150.4 (3)	C131—Ir2—C132—C133	−118.0 (5)
Cl1—Ir1—C61—C60	−116.5 (3)	C117—Ir2—C132—C133	66.5 (4)
C60—C61—C62—C63	5.4 (7)	C118—Ir2—C132—C133	60.5 (4)
Ir1—C61—C62—C63	−111.0 (4)	P4—Ir2—C132—C133	−27.4 (3)
C60—C61—C62—Ir1	116.4 (4)	P3—Ir2—C132—C133	153.2 (3)
C48—Ir1—C62—C61	3.4 (4)	Cl2—Ir2—C132—C133	−114.9 (3)
P2—Ir1—C62—C61	−85.9 (2)	C131—C132—C133—C134	140.1 (5)
P1—Ir1—C62—C61	89.2 (2)	Ir2—C132—C133—C134	−133.8 (4)
Cl1—Ir1—C62—C61	−178.9 (2)	C131—C132—C133—C138	−37.0 (6)
C48—Ir1—C62—C63	124.3 (3)	Ir2—C132—C133—C138	49.0 (6)
C61—Ir1—C62—C63	120.9 (5)	C138—C133—C134—C135	3.4 (7)
P2—Ir1—C62—C63	35.0 (3)	C132—C133—C134—C135	−173.9 (4)
P1—Ir1—C62—C63	−149.9 (3)	C133—C134—C135—C136	−1.4 (8)
Cl1—Ir1—C62—C63	−58.1 (3)	C134—C135—C136—C137	−1.2 (7)
C61—C62—C63—C68	30.5 (7)	C135—C136—C137—C138	1.5 (7)
Ir1—C62—C63—C68	−55.0 (6)	C136—C137—C138—C133	0.7 (7)
C61—C62—C63—C64	−148.0 (5)	C136—C137—C138—N4	178.6 (4)
Ir1—C62—C63—C64	126.6 (4)	C134—C133—C138—C137	−3.1 (6)
C68—C63—C64—C65	−3.8 (7)	C132—C133—C138—C137	174.1 (4)
C62—C63—C64—C65	174.8 (5)	C134—C133—C138—N4	179.1 (4)
C63—C64—C65—C66	0.8 (8)	C132—C133—C138—N4	−3.7 (6)
C64—C65—C66—C67	2.6 (8)	C125—N4—C138—C137	−107.4 (4)
C65—C66—C67—C68	−3.0 (8)	P4—N4—C138—C137	124.9 (4)
C66—C67—C68—C63	−0.2 (7)	C125—N4—C138—C133	70.5 (5)
C66—C67—C68—N2	−179.4 (4)	P4—N4—C138—C133	−57.2 (5)
C64—C63—C68—C67	3.5 (7)	C146—C141—C142—C143	2.5 (14)
C62—C63—C68—C67	−175.0 (4)	C141—C142—C143—C144	−2.4 (13)
C64—C63—C68—N2	−177.3 (4)	C142—C143—C144—C145	1.3 (11)
C62—C63—C68—N2	4.2 (7)	C143—C144—C145—C146	−0.4 (11)
C55—N2—C68—C67	109.2 (5)	C142—C141—C146—C145	−1.6 (12)
P2—N2—C68—C67	−123.0 (4)	C144—C145—C146—C141	0.5 (11)
C55—N2—C68—C63	−70.1 (5)	C156—C151—C152—C153	1 (2)
P2—N2—C68—C63	57.8 (5)	C151—C152—C153—C154	2 (3)
C131—Ir2—P3—O6	78.34 (18)	C152—C153—C154—C155	−5 (2)
C132—Ir2—P3—O6	117.06 (19)	C153—C154—C155—C156	6 (2)
C117—Ir2—P3—O6	−145.60 (18)	C154—C155—C156—C151	−4 (2)
C118—Ir2—P3—O6	−106.98 (18)	C152—C151—C156—C155	0 (2)
Cl2—Ir2—P3—O6	−15.01 (15)	C161—C162—C163—C164	70.4 (12)
C131—Ir2—P3—O5	−47.18 (17)	C162—C163—C164—C165	89.2 (11)
C132—Ir2—P3—O5	−8.46 (18)	C171—C172—C173—C174	162.7 (10)
C117—Ir2—P3—O5	88.88 (17)	C172—C173—C174—C175	82.0 (16)