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As pointed out earlier, the actual arrangement of layers in all close-packed
structures can be described in terms of the ABC notation for close-packing of
spheres. Thus the SiC type 6H has six Si and six C layers in its
hexagonal unit cell stacked as A
B
C
A
C
B
where the Roman letters denote positions of layers of Si atoms and the
Greek letters those of C atoms. Since the positions of C atoms are fixed
relative to the positions of Si atoms it is customary to omit the Greek letters
and write the structure as ABCACB. In the case of CdI2 structures, where
the Cd atoms lie in the octahedral voids between alternate close-packed iodine
layers, one often retains the Greek letters to denote the positions of Cd
layers. Thus CdI2 type 4H has a structure A
B C
B.
While this notation gives a complete description of the structure it does not
reveal the symmetry or lattice type directly and becomes cumbersome for
structures with large repeat periods.
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