MOLECULAR DESIGN FOR NOVEL SULFUR-COORDINATED TRANSITION METAL CLUSTERS. X.-T. Wu, Q. Huang, Q.-M. Wang, T.-L. Sheng, J.-X. Lu, State Key Laboratory of Structural Chemistry, Fujian Institute of Research or Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China
Molecular design for some novel molybdenum(tungsten)-copper(silver)-sulfur clusters is reported. The following clusters have been synthesized and characterized (1) Two novel octanuclear clusters [Et4N]4[M4Cu4Sl2O4] (M=Mo, W)
(2) Two novel dodecanuclear clusters [M4Cu4Sl2O4(CuTMEN)4] (M=Mo, W and TMEN=N,N,N',N'-Tetramethylethylendiamin).
(3) The novel double-chain cluster [S2WS2Ag(NH3C(CHOH)3(H2O)n.