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Structural analysis of anion-rich C-type Gd2O3 was carried by the Rietveld refinement of the powder X-ray diffraction data for compositions Gd0.8Ce0.2O1.60 and Gd0.6Ce0.4O1.70. The details of these two compositions are explained and compared with both the CeO2 structure and the Gd2O3 structure, i.e. the end member.