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Crystals of PrnB, the second enzyme in pyrrolnitrin biosynthesis are reported.


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The CuII atom in the title compound has a distorted trigonal–bipyramidal coordination environment defined by four N atoms from two bidentate 1,10-phenanthroline ligands and one oxygen atom from one-half of the monodentate N,N′-(1,4-phenylenedicarbonyl)diglycinate ligand. The dinuclear complex cations and the nitrate counter-anions as well as the solvate molecules are linked by an intricate network of hydrogen bonds.

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In the title salt hydrate, C2H10N22+·C12H10N2O62-·4H2O, each of the ions is located about a centre of inversion and the asymmetric unit is completed by two water molecules in general positons. In the crystal, the cations, anions and water molecules are connected by O-H
O and N-H
O hydrogen bonding into a three-dimensional network.



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The complex cation of the title compound, [Co(CO3)(C10H8N2)2]2(C12H10N2O6)·6H2O, contains a CoIII atom with a distorted octahedral coordination environment formed by four N atoms from two bidentate 2,2'-bipyridine ligands and one bidentate carbonate anion. The asymmetric unit is completed by one-half of the 2-({4-[(carboxylatomethyl)carbamoyl]phenyl}formamido)acetate dianion, which is located on a centre of inversion, and by three water molecules. Two [Co(CO3)(C10H8N2)2]+ cations are connected through C-H
O contacts by the uncoordinating anions. The aromatic rings of the 2,2'-bipyridine ligands and diacetate anions are involved in
-
stacking and C-H
interactions. The centroid-centroid distances are in the range 3.4898 (4)-3.6384 (5) Å. The crystal structure is stabilized by further O-H
O and N-H
O hydrogen bonds, which give rise to a three-dimensional supramolecular network.

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