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4 citations found for Brown, R.S.

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The title palladacycle, [Pd(C9H12N)Cl(C7H10N2)] or [Pd(DMBA)Cl(DMP)] [DMBA is 2-(dimethyl­amino)benzyl, N(CH3)2-CH2C6H4, and DMP is 4-(dimethyl­amino)pyridine, 4-N(CH3)2C5H4N], crystallizes with three crystallographically independent but conformationally almost identical mol­ecules (A, B and C) in the asymmetric unit. In all three mol­ecules, the Pd atoms are coordinated by slightly distorted square-planar arrays of two N (pyridine and amine), benzyl C and Cl atoms. The pyridine and amine N atoms are positioned trans to one another. The dihedral angles between benzene and pyridine rings are 7.47 (17), 7.34 (16) and 10.83 (15)° in mol­ecules A, B and C, respectively. In the crystal structure, weak intra- and inter­molecular C-H...N and C-H...Cl and C-H...[pi] inter­actions stabilize the structure.

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Acta Cryst. (1981). A37, C20
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The title compound, C15H15NS, crystallizes with two crystallographically independent and conformationally almost identical mol­ecules in the asymmetric unit. Both mol­ecules are non-planar, the dihedral angle between the two phenyl planes in each mol­ecule being 76.41 (11) and 86.65 (10)°. An anti conformation of the amide and thio groups is observed in the thio­amide fragment. In the solid state, the structure is stabilized by weak C—H...S intra­molecular inter­actions, inter­molecular N—H...S hydrogen bonds and C—H...π inter­actions.

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