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19 citations found for Tarantino, C.

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The title coordination polymer was obtained reacting zinc(II) acetate with a tetra­phospho­nate cavitand in DMF. The basic conditions of the reaction medium hydrolysed the cavitand making the phospho­nate group available for coordination to the zinc(II) cation.


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In the MgxCu1 - xCr2O4 solid solution, progressive substitution of the Jahn-Teller and d9 Cu2+ cation with the spherical and closed-shell Mg2+ cation results in a gradual reduction of the splitting of a and c unit-cell parameters, until transformation occurs from the tetragonal I41/amd to the cubic Fd\bar 3m archetype spinel structure. Tetragonal members of the series transform to cubic at high temperature, and the transition temperature decreases with increasing Mg content. The phase transition is first order in character for Cu-rich samples and evolves towards second-order character at intermediate compositions.

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The short-range structure of Mn1 - xFexNb2O6 columbites has been studied by Mössbauer and X-ray absorption spectroscopies. Length scales of observed local structural heterogeneities change across the solid solution.

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Acta Cryst A. (2016). A72, s269
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Acta Cryst A. (2012). A68, s50
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Acta Cryst A. (2013). A69, s455
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Acta Cryst A. (2012). A68, s197
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Acta Cryst. (2018). A74, e286
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Acta Cryst. (2007). A63, s293-s294
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Acta Cryst. (2007). A63, s293
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Acta Cryst. (2017). A73, C1383
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Acta Cryst. (2011). A67, C817
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Acta Cryst. (2018). A74, e124-e125
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